40134-72-3

Basic information

• Product Name: Cyclohexylethylmethylsilan
• Synonyms: Cyclohexylethylmethylsilan
• CAS NO: 40134-72-3
• Molecular Weight: 156.343
• Mol File: 40134-72-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexylethylmethylsilan(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexylethylmethylsilan(40134-72-3)
• EPA Substance Registry System: Cyclohexylethylmethylsilan(40134-72-3)

Safety Data

• Hazardous Substances Data: 40134-72-3(Hazardous Substances Data)

Upstream product

• 74-85-1 ethene 
• 2096-99-3 cyclohexyl(methyl)silane 

Relevant articles and documents

Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation

Chemo- and regioselectivity are often difficult to control during olefin hydrosilylation catalyzed by d- and f-block metal complexes. The cationic hydride of calcium [CaH]+ stabilized by an NNNN macrocycle was found to catalyze the regioselective hydrosilylation of aliphatic olefins to give anti-Markovnikov products, while aryl-substituted olefins were hydrosilyated with Markovnikov regioselectivity. Ethylene was efficiently hydrosilylated by primary and secondary hydrosilanes to give di- and monoethylated silanes. Aliphatic hydrosilanes were preferred over other commonly employed hydrosilanes: Arylsilanes such as PhSiH3 underwent scrambling reactions promoted by the nucleophilic hydride, while alkoxy- and siloxy-substituted hydrosilanes gave isolable alkoxy and siloxy calcium derivatives.