40164-53-2

Basic information

• Product Name: Benzene, 1,1'-(1-butyne-1,4-diyl)bis-
• Synonyms: (4-phenyl-1-butynyl)benzene;but-1-yne-1,4-diyldibenzene;4-phenyl-but-1-ynyl-benzene;1,4-diphenylbut-1-yne;(4-phenyl-3-butynyl)benzene;1,4-Diphenyl-but-1-in;1-phenethyl-2-phenylacetylene;Benzene,1,1'-(1-butyne-1,4-diyl)bis;1,4-diphenyl-1-butyne
• CAS NO: 40164-53-2
• Molecular Formula: C16H14
• Molecular Weight: 206.287
• Mol File: 40164-53-2.mol
• Article Data: 41

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-butyne-1,4-diyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-butyne-1,4-diyl)bis-(40164-53-2)
• EPA Substance Registry System: Benzene, 1,1'-(1-butyne-1,4-diyl)bis-(40164-53-2)

Safety Data

• Hazardous Substances Data: 40164-53-2(Hazardous Substances Data)

Upstream product

• 925-90-6 ethylmagnesium bromide 
• 536-74-3 phenylacetylene 
• 37595-74-7 N,N-phenylbistrifluoromethane-sulfonimide 
• 95607-27-5 1,4-diphenyl-2-(phenylsulfinyl)-1-butanone 
• 16520-62-0 4-Phenyl-1-butyne 
• 591-50-4 iodobenzene 
• 3757-88-8 tributylstannylethynylbenzene 
• 308796-14-7 phenethylzinc(II) bromide 
• 62-53-3 aniline 
• 84379-71-5 1,3-dioxoisoindolin-2-yl 3-phenylpropanoate 
• 100-52-7 benzaldehyde 
• 673-32-5 1-Phenylprop-1-yne 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 

Downstream Products

• 5407-91-0 1,4-diphenylbutan-1-one 
• 21772-11-2 1,4-diphenylbutan-3-yn-2-one 
• 40164-60-1 methyl 2,4-diphenylbutanoate 
• 117408-90-9 2-iodo-1-phenyl-3,4-dihydronaphthalene 
• 7469-40-1 1-phenyl-3,4-dihydronaphthalene 
• 1554260-30-8 diphenyl(1-phenyl-3,4-dihydronaphthalen-2-yl)phosphine oxide 

Relevant articles and documents

Tosyloxybenziodoxolone: A Platform for Performing the Umpolung of Alkynes in One-Pot Transformations

Ethynylbenziodoxolones (EBXs) are commonly encountered reagents for the electrophilic alkynylation of nucleophiles. Herein, we report a one-pot, two-step process for EBX generation and their direct application in substrate functionalization. Our approach enables us to bypass the originally mandatory isolation and purification of the reagents, resulting in a more efficient synthesis. We could apply this process to seven different transformations involving both two- and one-electron nucleophiles to obtain a large variety of alkynylated products.

Nickel-Catalyzed Sonogashira Coupling Reactions of Nonactivated Alkyl Chlorides under Mild Conditions

The two nickel chlorides1and2with [P,S] and [P,Se] bidentate ligands, respectively, were synthesized and used as catalysts for Sonogashira coupling reaction. Both1and2are efficient catalysts for Sonogashira C(sp3)-C(sp) coupling reactions. Comp

Metal-Free Visible-Light-Mediated Aromatization of 1,2–Dihydronaphthalenes

A series of polyaromatic naphthalenes have been synthesized through the dehydrogenation of the corresponding 1,2-dihydroarylnaphthalenes by using 9-mesityl-10-methylacridinium perchlorate as a photocatalyst and diphenyliodonium triflate as an external oxidant under visible light irradiation. The reaction proceeds smoothly under metal-free conditions and tolerates some functionalities. Interestingly, the reaction is also amenable to the aromatization of tetrahydronaphthalenes and fair conversions were obtained. Preliminary mechanistic investigations have been conducted and a reasonable mechanism is proposed.