40244-90-4 Usage
Description
Chlorodiisopropylphosphine, also known as (diisopropylphosphino)chloride, is a colorless to light yellow liquid with a pungent odor. It is an organophosphorus compound that is widely used in various chemical reactions and processes due to its unique properties and reactivity.
Uses
1. Used in Chemical Synthesis:
Chlorodiisopropylphosphine is used as a reagent for the synthesis of p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via a Grignard reaction. This reaction is crucial in the production of various organic compounds and pharmaceuticals.
2. Used as a Phosphination Reagent:
In the field of organometallic chemistry, chlorodiisopropylphosphine is used as a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine) for the zirconophosphination of alkynes. This process leads to the formation of zirconoalkenylphosphines, which are important intermediates in the synthesis of complex organic molecules.
3. Used in the Synthesis of Luminescent Complexes:
Chlorodiisopropylphosphine is also utilized in the synthesis of a luminescent mixed-donor platinum POCN pincer complex via a cyclometalation process. These complexes have potential applications in the field of optoelectronics and as sensors for various analytes.
4. Used in the Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, chlorodiisopropylphosphine can be used in the pharmaceutical industry for the synthesis of various drugs and drug candidates, particularly those involving organophosphorus chemistry.
5. Used in the Agrochemical Industry:
Similar to the pharmaceutical industry, chlorodiisopropylphosphine can be employed in the agrochemical industry for the synthesis of pesticides, herbicides, and other chemical products used in agriculture.
Check Digit Verification of cas no
The CAS Registry Mumber 40244-90-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 4,0,2,4 and 4 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 40244-90:
(7*4)+(6*0)+(5*2)+(4*4)+(3*4)+(2*9)+(1*0)=84
84 % 10 = 4
So 40244-90-4 is a valid CAS Registry Number.
InChI:InChI=1/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
40244-90-4Relevant articles and documents
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Ferron,J.L.
, p. 842 - 845 (1961)
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Haloalkylation process
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, (2008/06/13)
A process for the haloalkylation of certain tin, phosphorus and germanium halides is disclosed. The process is carried out typically in a halocarbon solvent at temperatures of less than 0° C. using as the haloalkylating reagent an admixture of a haloalkyl halide and tris(lower alkylamino)phosphine.
SYNTHESIS AND SOME PROPERTIES OF PHOSPHORYLATED FORMALS
Livantsov, M. V.,Proskurnina, M. V.,Prishchenko, A. A.,Lutsenko, I. F.
, p. 2237 - 2249 (2007/10/02)
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