403326-09-0

Basic information

• Product Name: [(μ-SCH₂)₂NCH₂Ph]Fe₂(CO)₆
• Synonyms: [(μ-SCH₂)₂NCH₂Ph]Fe₂(CO)₆
• CAS NO: 403326-09-0
• Molecular Weight: 477.081
• Mol File: 403326-09-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(μ-SCH₂)₂NCH₂Ph]Fe₂(CO)₆(CAS DataBase Reference)
• NIST Chemistry Reference: [(μ-SCH₂)₂NCH₂Ph]Fe₂(CO)₆(403326-09-0)
• EPA Substance Registry System: [(μ-SCH₂)₂NCH₂Ph]Fe₂(CO)₆(403326-09-0)

Safety Data

• Hazardous Substances Data: 403326-09-0(Hazardous Substances Data)

Upstream product

• 14243-23-3 (μ-dithio)bis(tricarbonyliron) 
• 100-46-9 benzylamine 
• 882697-72-5 benzyliminodimethanol 
• 50-00-0 formaldehyd 

Downstream Products

• 1021186-12-8 {(μ-SCH₂)₂NCH₂C₆H₅}Fe₂(CO)₅P(Pyr)₃ 
• 1333-74-0 hydrogen 
• 960078-98-2 Fe2(CO)4(μ-dppe)(μ-SCH2N(CH2C6H5)CH2S) 

Relevant articles and documents

An [Fe-Fe]-hydrogenase mimic immobilized on MCM-41 for the photochemical production of hydrogen in pure water

A composite proton-reducing catalyst Hy@MCM-41 was created by using a hydrophobic [Fe-Fe]-hydrogenase mimic (Hy) incorporated into the K +-exchanged molecular sieve MCM-41. Hy acts as the active site to generate H2 by reducing H+, and MCM-41 provide a large surface area to maintain the dispersion of Hy and to prevent aggregation and precipitation. Hy@MCM-41 was successfully applied to the light-induced hydrogen production in pure water with an iridium compound [Ir(ppy)2bpy]Cl and triethylamine (TEA) as the photosensitizer and the sacrificial electron donor, respectively, exhibiting good stability and catalytic activity. The present study provides a general strategy for the application of water-insoluble catalysts in pure water by using mesoporous molecular sieves. Copyright