4050-48-0Relevant articles and documents
Synthesis and characterization of a novel nanomagnetic phase-transfer catalyst and its application to regioselective synthesis of β-azido and β-nitro alcohols in water
Ayashi,Fallah-Mehrjardi,Kiasat
, p. 846 - 852 (2017/08/02)
Immobilization of polyethylene glycol-substituted 1-methylimidazolium bromide on the surface of magnetic Fe3O4 nanoparticles through hexane-1,6-diyldicarbamate linker afforded a powerful and reusable heterogeneous phase-transfer cata
Efficient kinetic bioresolution of 2-nitrocyclohexanol
Milner, Sinead E.,Brossat, Maude,Moody, Thomas S.,Elcoate, Curtis J.,Lawrence, Simon E.,Maguire, Anita R.
experimental part, p. 1011 - 1016 (2010/08/22)
The kinetic bioresolution of 2-nitrocyclohexanol 1 was investigated by screening a range of hydrolases both for enantioselective transesterification and for enantioselective hydrolysis of the corresponding acetate. By appropriate choice of biocatalyst and conditions, both enantiomers of cis and trans 2-nitrocyclohexanol 1 can be accessed in enantiopure form.
Micellar media for the efficient ring opening of epoxides with CN-, N3-, NO3-, NO2-, SCN-, Cl- and Br- catalyzed with Ce(OTf)4
Iranpoor, Nasser,Firouzabadi, Habib,Shekarize, Marzieh
, p. 724 - 727 (2007/10/03)
Micellar media are introduced for the efficient ring opening of epoxides with sodium salts of nucleophiles such as CN, N3-, NO3-, NO2, SCN, Br and Cl-, catalyzed with Ce(OTf)4. This method is an efficient procedure for the synthesis of different β-substituted alcohols under mild reaction conditions. The reaction with SCN- is an easy procedure for the high yielding preparation of epoxy sulfides.
