40523-67-9

Basic information

• Product Name: trans-6-methylcyclohex-2-en-1-ol
• Synonyms: trans-6-methylcyclohex-2-en-1-ol
• CAS NO: 40523-67-9
• Molecular Weight: 112.172
• Mol File: 40523-67-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-6-methylcyclohex-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: trans-6-methylcyclohex-2-en-1-ol(40523-67-9)
• EPA Substance Registry System: trans-6-methylcyclohex-2-en-1-ol(40523-67-9)

Safety Data

• Hazardous Substances Data: 40523-67-9(Hazardous Substances Data)

Upstream product

• 75337-05-2 4-methyl-2-cyclohexenone 
• 591-47-9 4-methylcyclohexene 
• 62392-84-1 (+)-(R)-6-methylcyclohex-2-en-1-one 
• 124021-39-2 (+/-)-trans-2-acetoxy-1-methyl-cyclohexene-⁽³⁾ 

Downstream Products

• 7443-52-9 (+/-)-trans-2-methylcyclohexanol 
• 78168-31-7 (2RS)-N,N-Diethyl-2<(1SR,4SR)-4-Methyl-2-cyclohexenyl>propanamide 
• 78215-31-3 (2RR)-N,N-Diethyl-2<(1SS,4SS)-4-Methyl-2-cyclohexenyl>propanamide 
• 6610-21-5 6-methylcyclohex-2-en-1-one 

Relevant articles and documents

Regioselectivity in the palladium-catalyzed addition of carbon nucleophiles to carbocyclic derivatives

The regioselectivity of Pd-catalyzed malonate additions and arylations to cycloalkenyl esters can be predicted by completing a stereochemical analysis of the Pd-π-allyl complex. The Pd-catalyzed malonate additions which have the greatest degree of regioselectivity are in which substituents have a steric influence in blocking the incoming nucleophile. Cyclopentenyl substrates displayed lower regioselectivity than the cyclohexyl counterparts presumably due to increased planarity of the system. Arylations using tin and hypervalent silicon reagents were compared.