4060-05-3Relevant articles and documents
A novel low-molecular-mass pumpkin polysaccharide: Structural characterization, antioxidant activity, and hypoglycemic potential
Huang, Linlin,Li, Fei,Li, Quanhong,Liang, Li,Wei, Yunlu,Yu, Guoyong
, (2020/10/02)
The novel natural low-molecular-mass polysaccharide (SLWPP-3) from pumpkin (Cucurbia moschata) was separated from the waste supernatant after macromolecular polysaccharide production and purified using a DEAE cellulose-52 column and gel-filtration chromatography. Chemical and instrumental studies revealed that SLWPP-3 with a molecular mass of 3.5 kDa was composed of rhamnose, glucose, arabinose, galactose and uronic acid with a weight ratio of 1: 1: 4: 6: 15, and primarily contained →3,6)-β-D-Galp-(1→, →4)-α-GalpA-(1→(OMe), →4)-α-GalpA-(1→, →2,4)-α-D-Rhap-(1→, →3)-β-D-Galp-(1→, →4)-α-D-Glcp, and →4)-β-D-Galp residues in the backbone. The branch chain passes were connected to the main chain through the O-4 atom of glucose and O-3 atom of arabinose. Physiologically, the ability of SLWPP-3 to inhibit carbohydrate-digesting enzymes and DPPH and ABTS radicals, as well as protect pancreatic β cells from oxidative damage by decreasing MDA levels and increasing SOD activities, was confirmed. The findings elucidated the structural types of pumpkin polysaccharides and revealed a potential adjuvant natural product with hypoglycemic effects.
Allelopathic effect of triterpenoid saponins from the stems of lathyrus aphaca linn
Yadava, Raj N.,Asati, Nidhi
, p. 177 - 184 (2018/09/14)
Two new triterpenoid saponins have been isolated from the methanolic extract of the stems of the Lathyrus aphaca Linn. A new compound 1 has m.p. 295?297°C, m.f. C47H78O16, [M]+ m/z 898 was characterized as 3-O-[β-D-galactopyranosyl-(14)]-β-D-xylopyranosyl-3β,11α,28-trihydroxy-olean-12-ene-28-O-α-L-rhamnopyranoside and compound 2 has m. p. 289-291°C, m.f. C46H76O16, [M]+ m/z 884 was characterized as 3-O-[β-D-xylopyranosyl-(1→4)]-β-D-glucopyranosyl-(1→4) α-L-arabinofuranosyl 2α,3β,19α-trihydroxy-olean-12-ene by various color reactions, chemical degradations, and spectral analysis. From experimental findings, it was concluded that both compounds 1 and 2 have shown allelopathic effects on the growth of shoot length of the seeds of Zea mays (L.).
New antifungal triterpenoid saponin from launaea pinnatifida cass
Yadava,Chakravarti
experimental part, p. 83 - 87 (2009/12/06)
A new triterpenoid saponin (compound 1), 3β-O-[α-L- rhamnopyranosyI-(l→3)-O-α-L-arabinopyranosyl-(l→3) -O-β-D-galactopyranosyl]-spergulatriol along with known compounds glutenol and hopenol-b have been isolated from the methanol soluble fraction of the defatted seeds of the plant and structurally elucidated by various colour reactions, chemical degradations and spectral analysis. Compound 1 shows antifungal activity against various fungi.