40634-95-5

Basic information

• Product Name: trimethylsilyl cis-2-isocyanato-4-cyclohex-1-ene carboxylate
• CAS NO: 40634-95-5
• Molecular Weight: 239.346
• Mol File: 40634-95-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: trimethylsilyl cis-2-isocyanato-4-cyclohex-1-ene carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: trimethylsilyl cis-2-isocyanato-4-cyclohex-1-ene carboxylate(40634-95-5)
• EPA Substance Registry System: trimethylsilyl cis-2-isocyanato-4-cyclohex-1-ene carboxylate(40634-95-5)

Safety Data

• Hazardous Substances Data: 40634-95-5(Hazardous Substances Data)

Upstream product

• 4648-54-8 trimethylsilylazide 
• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 85-43-8 1,2,3,6-Tetrahydrophthalic anhydride 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 129884-38-4 (1R,2S)-Cyclohex-4-ene-1,2-diamine; compound with sulfuric acid 
• 102312-67-4 cis-cyclohex-3-enyl-1,2-diamine dihydrochloride 
• 57266-59-8 cis-2-isocyanatocyclohex-4-ene-1-carbonyl chloride 
• 57266-56-5 (1R*,6S*)-6-aminocyclohex-3-ene-1-carboxylic acid hydrochloride 
• 24716-92-5 (±)-cis-2-aminocyclohexane-1-carboxylic acid hydrochloride 
• 54867-11-7 cis-2-(4'-methylbenzenesulphonylamino)cyclohexane-N-methylcarboxamide 
• 54867-10-6 (+/-)-cis-2-(toluene-4-sulfonylamino)-cyclohexane carboxylic acid 
• 54867-17-3 cis-2-aminocyclohexane-N-methylcarboxamide 
• 54867-18-4 cis-1-amino-2-methylaminomethylcyclohexane 

Relevant articles and documents

Access to amphiphilic cis-configurated polyamide-3 using alcohols as initiators

The synthesis of polyamide-3 from 4a,5,8,8a-tetrahydro-1H-benzo[d][1,3]oxazine-2,4-dione (β-NCA, 1) using methanol, dye (Disperse Red 13), and poly(ethylene glycol) as initiator is described. The ring-opening polymerization under release of CO2 produces polyamides-3 with definite terminal groups, high purity, and relatively narrow dispersity. This route was used for preparation of block copolymers from as an example.

2-Methyl-4,5-dihydroimidazole as a Doubly Nucleophilic Unit: Preparation of Dihydroimidazole Azaprostanoids

2-Methyl-4,5-dihydroimidazole is incorporated as a doubly nucleophilic synthon, by successive alkylations at N-1 and C-2(Me), into monocyclic 9,12- and 8,11-diazaprostanoids containing the dihydroimidazole moiety. 2-Methyl-3a,4,7,7a-tetrahydrobenzimidazole is prepared (from 1,2,3,6-tetrahydrophthalic anhydride) and elaborated in the same way into a diazaprostacyclin precursor.

Stereocontrolled Syntheses for the Six Diastereomeric 1,2-Dihydroxy-4,5-diaminocyclohexanes: PtII Complexes and P-388 Antitumor Properties

Stereocontrolled syntheses for the six diastereomeric 1,2-dihydroxy-4,5-diaminocyclohexanes 3a-f from cyclohexene diamines cis-4 and trans-5 are described.Cbz-protected species cis-9 and trans-11, respectively, served as a source of stable Cbz-protected p