408317-19-1

Basic information

• Product Name: [Ag(hexakis(tolylsulfanyl)benzene)(2-butanone)PF₆
• CAS NO: 408317-19-1
• Molecular Weight: 1136.2
• Mol File: 408317-19-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ag(hexakis(tolylsulfanyl)benzene)(2-butanone)PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [Ag(hexakis(tolylsulfanyl)benzene)(2-butanone)PF₆(408317-19-1)
• EPA Substance Registry System: [Ag(hexakis(tolylsulfanyl)benzene)(2-butanone)PF₆(408317-19-1)

Safety Data

• Hazardous Substances Data: 408317-19-1(Hazardous Substances Data)

Upstream product

• 26042-63-7 silver(I) hexafluorophosphate 
• 55709-41-6 hexakis(4-methyl-1-phenylthio)benzene 
• 78-93-3 butanone 

Relevant articles and documents

A zigzag chain coordination polymer consisting of silver(I) ion having square planar geometry

Silver(I) complexes of hexakis(tolylsulfanyl)benzene (htsb), [Ag(htsb)](PF6) (1), have been prepared and their molecular structures were determined by X-ray crystallography. In 1, the silver ion prefers a square planar coordination geometry comprized of four S atoms from two different htsb molecules and producing a zigzag chain structure of Ag-S in the silver coordination polymer. Based on the thermo-gravimetry analysis results, two tolylsulfanyl groups were easily eliminated at approximately 211°C. However, [Ag(htsb)(2-butanone)] (PF6) (2), which were obtained by the reactions in different solvents, showed a different colors and thermal degradation behaviors.