40870-69-7 Usage
General Description
2,3-Dimethyl-5-acetoxymethyl-p-benzoquinone is a chemical compound that belongs to the class of para-benzoquinone derivatives. It is a yellow crystalline solid that is commonly used in organic synthesis as a reagent for the selective oxidation of alcohols to carbonyl compounds. It is also employed as a co-catalyst in the preparation of various organic materials, such as resins, polymers, and adhesives. Additionally, it has been studied for its potential applications in the field of medicine, particularly as an anti-tumor agent due to its ability to induce apoptosis in cancer cells. However, proper safety precautions should be taken when handling this compound, as it can be hazardous if not used responsibly.
Check Digit Verification of cas no
The CAS Registry Mumber 40870-69-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 4,0,8,7 and 0 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 40870-69:
(7*4)+(6*0)+(5*8)+(4*7)+(3*0)+(2*6)+(1*9)=117
117 % 10 = 7
So 40870-69-7 is a valid CAS Registry Number.
InChI:InChI=1/C11H12O4/c1-6-7(2)11(14)9(4-10(6)13)5-15-8(3)12/h4H,5H2,1-3H3
40870-69-7Relevant articles and documents
Choice of Manganese(III) Complexes for the Synthesis of 4,4'-Biphenyldiols and 4,4'-Diphenoquinones
Nishino, Hiroshi,Nobuyuki, Itoh,Nagashima, Makiko,Kurosawa, Kazu
, p. 620 - 622 (2007/10/02)
2,6-Disubstituted phenols are oxidized with tris(2,4-pentanedionato)manganese(III), , in glacial acetic acid to give the corresponding 4,4'-biphenyldiols in high yields, whereas similar reactions using manganase(III) acetate, , instead of quantitatively yield the corresponding 4,4'-diphenoquinones.Cross-coupling reactions of 2,6-di-t-butylphenol and other substituted phenols afford the corresponding cross-coupled 4,4'-biphenyldiols and 4,4'-diphenoquinones together with oxidation products derived from them starting phenols themselves.The advantageous use of and Mn(OAc)3> in the ubiqitous phenol coupling reaction is discussed.
