41034-90-6

Basic information

• Product Name: DIETHYL(2-FURYLMETHYL)AMINE
• Synonyms: DIETHYL(2-FURYLMETHYL)AMINE;N-ETHYL-N-(2-FURYLMETHYL)ETHANAMINE
• CAS NO: 41034-90-6
• Molecular Formula: C9H15NO
• Molecular Weight: 0
• Mol File: 41034-90-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 175.5°C at 760 mmHg
• Flash Point: 59.9°C
• Appearance: /
• Density: 0.946g/cm³
• Vapor Pressure: 1.15mmHg at 25°C
• Refractive Index: 1.476
• CAS DataBase Reference: DIETHYL(2-FURYLMETHYL)AMINE(CAS DataBase Reference)
• NIST Chemistry Reference: DIETHYL(2-FURYLMETHYL)AMINE(41034-90-6)
• EPA Substance Registry System: DIETHYL(2-FURYLMETHYL)AMINE(41034-90-6)

Safety Data

• Hazardous Substances Data: 41034-90-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H15NO/c1-3-10(4-2)8-9-6-5-7-11-9/h5-7H,3-4,8H2,1-2H3

Upstream product

• 109-89-7 diethylamine 
• 98-01-1 furfural 
• 13686-66-3 N,N-diethylaminodimethylsilane 
• 32488-17-8 N,N-diethyl furan 2-carboxamide 
• 88-14-2 2-furanoic acid 

Relevant articles and documents

Silicon hydrogenation reaction method of organic boron and inorganic alkali catalysis amide (by machine translation)

The method is characterized in that organic boron and inorganic bases are used as catalysts, silane is used as a reducing agent, primary amide is reduced to primary amine or dehydration dinitrile, the secondary amide is reduced to a secondary amine or aldimine, and the tertiary amide is reduced to tertiary amine. The method has the advantages of simple operation, mild reaction conditions, wide substrate universality, good functional group compatibility and the like, and has the characteristics of good stability, cheap and accessible catalyst, simple and convenient operation, high practicality and the like. (by machine translation)

A BEt3-Base Catalyst for Amide Reduction with Silane

Reported herein is the development of a simple but practical catalytic system for the selective reduction of amides with hydrosilane or hydrosiloxane. Low-cost and readily available triethylborane (1.0 M in THF), in combination with a catalytic amount of an alkali metal base, was found to catalyze the reduction of all three amide classes (tertiary, secondary, and primary amides) to form amines under mild conditions. In addition, the selective transformation of secondary amides to aldimines and primary amides to nitriles can also be achieved by using a proper combination of BEt3 and base. The scope of these BEt3-base-catalyzed amide hydrosilylation reactions has been explored in depth. Preliminary results of mechanistic studies suggest a modified Piers' silane Si-H···B activation mode wherein the hydride abstraction by BEt3 is promoted by the coordination of an alkoxide or hydroxide anion to the Si center.

Efficient biomass pretreatment using ionic liquids derived from lignin and hemicellulose

Ionic liquids (ILs), solvents composed entirely of paired ions, have been used in a variety of process chemistry and renewable energy applications. Imidazolium-based ILs effectively dissolve biomass and represent a remarkable platform for biomass pretreat