41049-47-2Relevant articles and documents
OXIDATION OF ALKENES BY THE Pb(IV)-I2-CF3COOH SYSTEM
Gutsulyak, R. B.,Serguchev, Yu. A.
, p. 1383 - 1388 (2007/10/02)
The Pb(OAc)4-I2-CF3COOH oxidizing system was discovered, and its reactions with alkenes (cyclohexene, 1-hexene, styrene) in 1,2,2-trifluorotrichloroethane led to the selective formation of β-iodoalkyl trifluoroacetates or the ditrifluoroacetates of diols.In the reaction with 1-hexene a third direction is possible, i.e., the formation of the mixed acetic acid and trifluoroacetic diesters of 1,2-hexanediol.During the oxidation of styrene the formation of the geminal diester 1,1-ditrifluoroacetoxy-2-phenylethane is observed.The reaction takes place with the intermediate formation of compounds of monovalent iodine or a complex of polyvalent iodine, depending on the ratio of the reagents.
NOVEL REAGENTS CONTAINING HYPERVALENT IODINE AND THEIR USE FOR ELECTROPHILIC ADDITIONS TO OLEFINS
Zefirov, Nikolai S.,Zhdankin, Viktor V.,Dan'kov, Yu. V.,Caple, Ronald,Berglund, Bruce A.
, p. 3971 - 3974 (2007/10/02)
A series of novel I(III) containing reagents have been developed and their electrophilic reactions with olefins giving vic-disubstituted derivatives (including vic-ditriflates) are described.