41103-85-9

Basic information

• Product Name: (R,E)-1-methyl-4-(styrylsulfinyl)benzene
• Synonyms: (R,E)-1-methyl-4-(styrylsulfinyl)benzene
• CAS NO: 41103-85-9
• Molecular Weight: 242.342
• Mol File: 41103-85-9.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: (R,E)-1-methyl-4-(styrylsulfinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-1-methyl-4-(styrylsulfinyl)benzene(41103-85-9)
• EPA Substance Registry System: (R,E)-1-methyl-4-(styrylsulfinyl)benzene(41103-85-9)

Safety Data

• Hazardous Substances Data: 41103-85-9(Hazardous Substances Data)

Upstream product

• 61735-44-2 1-Chloro-1-phenyl-2-(toluenesulfinyl)ethan 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 536-74-3 phenylacetylene 
• 103-64-0 bromostyrene 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 646516-62-3 cholesteryl (R_S)-(E)-2-phenylethenesulfinate 
• 7526-26-3 diphenyl methylphosphonate 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 
• 100-52-7 benzaldehyde 
• 1017-88-5 dimethyldiphenylphosphonium iodide 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 68695-49-8 α-dimethylphosphoryl methyl p-tolyl sulfoxide 
• 34125-84-3 chloromethyl p-tolyl sulfide 

Downstream Products

• 622-63-9 ethyl p-tolyl sulfide 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 118653-58-0 (1S,SR)-N-benzyl-<1-phenyl-2-(p-tolylsulfinyl)ethyl>amine 
• 118620-49-8 (1R,SR)-N-benzyl-<1-phenyl-2-(p-tolylsulfinyl)ethyl>amine 
• 137603-99-7 1-(1-Allyl-2-phenyl-pent-4-enylsulfanyl)-4-methyl-benzene 
• 3699-01-2 4-tolyl phenyl sulfide 
• 257904-87-3 (E)-(Ss,3S)-(+)-3-acetoxy-1,5-diphenyl-2-(p-tolylsulfinyl)-1-pentene 
• 257904-84-0 (E)-(Ss,1R)-(+)-1-acetoxy-1-(2-naphthyl)-3-phenyl-2-(p-tolylsulfinyl)-2-propene 
• 257904-86-2 (E)-(Ss,1S)-(-)-1-acetoxy-1-(2-naphthyl)-3-phenyl-2-(p-tolylsulfinyl)-2-propene 
• 131226-02-3 3-Phenyl-2-((R)-toluene-4-sulfinyl)-hexahydro-pyrazolo[1,2-a]pyridazin-1-one 
• 131226-03-4 Cis-1,5-diaza-3-p-tolylthio-4-phenylbicyclo<4.3.0>nonan-2-one 
• 131226-03-4 (2S,3S)-3-Phenyl-2-p-tolylsulfanyl-hexahydro-pyrazolo[1,2-a]pyridazin-1-one 
• 112020-25-4 (S)-4-phenyl-1,5-diazacyclononan-2-one 
• 112020-27-6 (R)-4-phenyl-1,5-diazacyclononan-2-one 

Relevant articles and documents

Asymmetric Induction in the Reaction of a Chiral Lithiated Sulphoxide and Aldehydes

Significant asymmetric induction has been observed in the reaction of 1-lithio-2-phenyl-1-(R)-p-tolylsulphinylethylene; the sense of this induction has been established by an X-ray structure on one of the products.

Visible-light-induced selective synthesis of sulfoxides from alkenes and thiols using air as the oxidant

A highly selective synthesis of sulfoxides from alkenes and thiols was established by visible-light photoredox catalysis at room temperature. This metal-free transformation protocol, which uses inexpensive Rose Bengal as the photocatalyst and air as the green oxidant, opens a new door toward the facile and practical construction of sulfoxides.

Stereoselective heck reactions with vinyl sulfoxides, sulfides and sulfones

We report the Heck cross-coupling of notoriously unreactive, but synthetically valuable olefins: vinyl sulfoxides, vinyl sulfones, and vinyl sulfides. Key findings include the importance of the sterically hindered (tri-tert-butyl)phosphine ligand and the unique effectiveness of triethylamine as the base. The method is general, E-selective, and can be used to synthesize disubstituted or trisubstituted olefins through simple adjustments of stoichiometry. Copyright