411238-08-9

Basic information

• Product Name: Cyclopentanecarboxylic acid, 1-(2-propenyl)- (9CI)
• Synonyms: Cyclopentanecarboxylic acid, 1-(2-propenyl)- (9CI)
• CAS NO: 411238-08-9
• Molecular Formula: C9H14O2
• Molecular Weight: 154.20626
• Product Categories: CARBOXYLICACID
• Mol File: 411238-08-9.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 248.7±9.0 °C(Predicted)
• Appearance: /
• Density: 1.037±0.06 g/cm3(Predicted)
• PKA: 4.86±0.20(Predicted)
• CAS DataBase Reference: Cyclopentanecarboxylic acid, 1-(2-propenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanecarboxylic acid, 1-(2-propenyl)- (9CI)(411238-08-9)
• EPA Substance Registry System: Cyclopentanecarboxylic acid, 1-(2-propenyl)- (9CI)(411238-08-9)

Safety Data

• Hazardous Substances Data: 411238-08-9(Hazardous Substances Data)

Upstream product

• 3400-45-1 cyclopentanecarboxylic acid 
• 106-95-6 allyl bromide 
• 35466-83-2 allyl methyl carbonate 
• 153579-96-5 methyl 1-allylcyclopentane-1-carboxylate 
• 4630-80-2 methyl cyclopentane carboxylate 

Downstream Products

• 152090-71-6 1-Acetyl-1-(2-propenyl)cyclopentane 

Relevant articles and documents

Radical Aryl Migration from Boron to Carbon

Radical aryl migration reactions represent a unique type of organic transformations that involve the intramolecular migration of an aryl group from a carbon or heteroatom to a C- or heteroatom-centered radical through a spirocyclic intermediate. Various elements, including N, O, Si, P, S, Sn, Ge, and Se, have been reported to participate in radical aryl migrations. However, radical aryl migration from a boron center has not been reported to date. In this communication, radical 1,5-aryl migration from boron to carbon in aryl boronate complexes is presented. C-radicals readily generated through radical addition onto alkenyl aryl boronate complexes are shown to engage in 1,5-aryl migration reactions to provide 4-aryl-alkylboronic esters. As boronate complexes can be generatedin situby the reaction of alkenylboronic acid esters with aryl lithium reagents, the aryl moiety is readily varied, providing access to a series of arylated products starting from the same alkenylboronic acid ester via divergent chemistry. Reactions proceed with high diastereoselectivity under mild conditions, and also the analogous 1,4-aryl shifts are feasible. The suggested mechanism is supported by DFT calculations.

Preparation of cyclic imides from alkene-tethered amides: Application of homogeneous Cu(ii) catalytic systems

A Cu-based homogeneous catalytic system was proposed for the preparation of imides from alkene-tethered amides. Here, O2 acted as a terminal oxidant and a cheap and easily available oxygen source. The cleavage of CC bonds and the formation of C

5-HYDROXYTRYPTAMINE RECEPTOR 7 MODULATORS AND THEIR USE AS THERAPEUTIC AGENTS

Pharmaceutical compositions of the invention comprise functionalized lactone derivatives having a disease-modifying action in the treatment of diseases associated with dysregulation of 5-hydroxytryptamine receptor 7 activity.