41173-24-4

Basic information

• Product Name: Benzene, 1-chloro-2-[2-(phenylsulfonyl)ethenyl]-, (E)-
• CAS NO: 41173-24-4
• Molecular Formula: C14H11ClO2S
• Molecular Weight: 278.759
• Mol File: 41173-24-4.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-2-[2-(phenylsulfonyl)ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-2-[2-(phenylsulfonyl)ethenyl]-, (E)-(41173-24-4)
• EPA Substance Registry System: Benzene, 1-chloro-2-[2-(phenylsulfonyl)ethenyl]-, (E)-(41173-24-4)

Safety Data

• Hazardous Substances Data: 41173-24-4(Hazardous Substances Data)

Upstream product

• 3752-25-8 o-chlorocinnamic acid 
• 873-55-2 sodium benzenesulfonate 
• 873-31-4 2-chlorophenylacetylene 
• 108-98-5 thiophenol 
• 89-98-5 2-chloro-benzaldehyde 
• 401514-40-7 1-chloro-2-(2,2-dibromovinyl)benzene 
• 704-96-1 trans-2-chlorocinnamic acid 
• 80-17-1 benzenesufonyl hydrazide 
• 24654-08-8 3-(2-chlorophenyl)prop-2-ynoic acid 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 56069-39-7 diethyl phenylsulfonylmethylphosphonate 
• 2039-87-4 2-chlorostyrene 
• 3959-23-7 benzenesulfonylacetic acid 
• 62717-50-4 o-chlorostyrene oxide 

Downstream Products

• 1245924-62-2 1-((2S,3R)-3-(2-((S)-p-tolylsulfinyl)phenyl)-4-phenyl-1-(phenylsulfonyl)butan-2-yl)-2-chlorobenzene 
• 1245924-52-0 1-(2-[(2R,3S)-3-(2-chlorophenyl)-4-(phenylsulfonyl)butan-2-yl](S)-phenylsulfinyl)-4-methylbenzene 

Relevant articles and documents

Intermolecular [2 + 2] Photocycloaddition of α,β-Unsaturated Sulfones: Catalyst-Free Reaction and Catalytic Variants

2-Aryl-1-sulfonyl-substituted cyclobutanes were prepared in an intermolecular [2 + 2] photocycloaddition from various α,β-unsaturated sulfones and olefins upon irradiation at λ = 300 nm (26 examples, 60-99% yield). Lewis acids catalyzed the [2 + 2] photocycloaddition of 2-benzimidazolyl styryl sulfones. At short wavelengths, the latter substrates underwent C-S bond cleavage but AlBr3 (5 mol %) allowed for an intermolecular reaction with 2,3-dimethyl-2-butene at longer wavelengths. A chiral-at-metal Lewis acid (2 mol %) facilitated an enantioselective reaction (up to 77% ee).

Visible-light-induced decarboxylative sulfonylation of cinnamic acids with sodium sulfinates by using Merrifield resin supported Rose Bengal as a catalyst

A visible-light-induced decarboxylative sulfonylation of cinnamic acids with sodium sulfinates for the synthesis of vinyl sulfones was developed. The reaction proceeded smoothly in the presence of Merrifield resin supported Rose Bengal ammonium salt as a

A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

A new mode of S-O bond activation has been discovered, which constitutes novel reactivity of easily available and bench-stable arylsulfonate phenol esters. This protocol enables access to putative sulfonyl radical intermediates, which enable straightforward access to valuable vinyl sulfones.