412356-83-3Relevant articles and documents
Synthesis of kinetically stabilized silaneselone and silanetellone
Tokitoh, Norihiro,Sadahiro, Tomonori,Hatano, Ken,Sasaki, Takayo,Takeda, Nobuhiro,Okazaki, Renji
, p. 34 - 35 (2007/10/03)
Kinetically stabilized silaneselone [Tbt(Dip)Si=Se (4); Tbt=2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Dip=2,6-diisopropylphenyl] and silanetellone [Tbt(Dip)Si=Te] were synthesized by direct chalcogenation of Tbt(Dip)M: (M=Si, Ge) with elemental chalcogen. Deselenation of Tbt(Dip)SiSe2 also gave 4. Metallanetellones [Tbt(Dip)M=Te; M=Si, Ge] were also synthesized by the reaction of Tbt(Dip)MLi2 (M=Si, Ge) with TeCl2, which is a new synthetic method for heavy ketones.