41572-08-1

Basic information

• Product Name: tetrakis(trimethylsilylmethyl)vanadium
• Synonyms: tetrakis(trimethylsilylmethyl)vanadium
• CAS NO: 41572-08-1
• Molecular Weight: 399.809
• Mol File: 41572-08-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetrakis(trimethylsilylmethyl)vanadium(CAS DataBase Reference)
• NIST Chemistry Reference: tetrakis(trimethylsilylmethyl)vanadium(41572-08-1)
• EPA Substance Registry System: tetrakis(trimethylsilylmethyl)vanadium(41572-08-1)

Safety Data

• Hazardous Substances Data: 41572-08-1(Hazardous Substances Data)

Upstream product

• 131063-11-1 Vanadium (III) chloride-(tris-tetrahydrofuran) 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 

Relevant articles and documents

SYNTHESIS AND PROPERTIES OF COVALENT TRI- AND TETRAVALENT VANADIUM

Reactions of VCl3*3THF with RMgX (R = Ph, CH2SiMe3, C6F5) in various ratios have been studied.The stable compounds R3V*THF (R = CH2SiMe3, C6F5) were obtained.The chemical properties of R3V*THF, R4V*2L (R = CH2Ph, L = Et2O; R = C6F5, L = THF) and (Me3SiCH2)4V were investigated.Cleavage of the vanadium-carbonium ?-bond occurs in reactions with H2O, HCl and HgCl2.The insertion of carbon dioxide into the vanadium-carbon ?-bond was investigated.A scheme for the derivatives of tri- and tetravalent vanadium is proposed.Oxidative addition to (C6F5)3V*THF by Ph3CCl and VCl3*3THF was also studied.