41654-12-0

Basic information

• Product Name: (E)-3-Methyl-3-pentenoic acid methyl ester
• Synonyms: (E)-3-Methyl-3-pentenoic acid methyl ester
• CAS NO: 41654-12-0
• Molecular Formula: C₇H₁₂O₂
• Molecular Weight: 0
• Mol File: 41654-12-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (E)-3-Methyl-3-pentenoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-Methyl-3-pentenoic acid methyl ester(41654-12-0)
• EPA Substance Registry System: (E)-3-Methyl-3-pentenoic acid methyl ester(41654-12-0)

Safety Data

• Hazardous Substances Data: 41654-12-0(Hazardous Substances Data)

Upstream product

• 802294-64-0 propionic acid 
• 98962-77-7 (3RS,4RS)-3,4-epoxy-3-methyl-valeric acid methyl ester 
• 186581-53-3 diazomethane 
• 89180-83-6 2,3-dibromo-2-methyl-butyryl chloride 
• 89851-92-3 4,5-dimethyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid methyl ester 
• 51302-90-0 Methyl 3-hydroxy-3-methylpentanoate 
• 23806-24-8 3-methyl-2-thiophenecarboxylic acid 
• 710326-36-6 3,4-dibromo-3-methyl-2-pentanone 
• 124-41-4 sodium methylate 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 565-62-8 3-methylpent-3-en-2-one 
• 53496-45-0 4-hydroxy-3-methyl-pentan-2-one 
• 86769-75-7 (3S,4R)-3-Methyl-4-phenylsulfanyl-pentanoic acid methyl ester 

Downstream Products

• 41653-93-4 trans-Δ²-3-methylpentenoic acid 
• 108-24-7 acetic anhydride 

Relevant articles and documents

O-SILYLATED ENOLATES IN ORGANIC SYNTHESIS: SULPHUR-MEDIATED ALKYLATION OF ESTERS WITH ALKENES.

O-Silylated ester enolates can be alkylated, under ZnBr2-catalysis, by the PhSCl-adducts of mono- and di-substituted alkenes to give γ-phenylthioesters, from which sulphur can be removed both reductively and oxidatively.This alkene carbosulphenylation rea

Mevalonic acid analogs as inhibitors of cholesterol biosynthesis

A series of 20 mevalonic acid analogs were synthesized and tested for their ability to inhibit cholesterol biosynthesis from [2-14C]-mevalonate in rat liver homogenates. Removal of the 5-hydroxyl group from mevalonic acid produced an active inhibitor, 3-hydroxy-3-methylpentanoic acid. Removal of the 3-hydroxyl group, addition of an aromatic group in the 3-position, or insertion of a double bond reduced inhibitory activity. Compounds with an aromatic group or halide on the 5-position were active inhibitors. The most active inhibitor was 5-phenylpentanoic acid, with 50% inhibition at 0.064 mM.