41801-83-6Relevant articles and documents
Accessing novel fluorinated heterocycles with the hypervalent fluoroiodane reagent by solution and mechanochemical synthesis
Browne, Duncan L.,Jones, Andrew C.,Riley, William,Singh, Kuldip,Stuart, Alison M.
supporting information, p. 7406 - 7409 (2021/08/03)
A new and efficient strategy for the rapid formation of novel fluorinated tetrahydropyridazines and dihydrooxazines has been developed by fluorocyclisation of β,γ-unsaturated hydrazones and oximes with the fluoroiodane reagent. Mechanochemical synthesis d
Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: Application to the synthesis of the C13-C21 fragment of palmerolide A
Wen, Zhen-Kang,Xu, Yun-He,Loh, Teck-Peng
supporting information, p. 13284 - 13287,4 (2012/12/12)
Diene to meet: A palladium-catalyzed cross-coupling reaction between alkyl-substituted olefins and acrylates gives the corresponding butadienes in moderate yield and stereoselectivity. This atom-economical reaction, which forms C sp 2-C sp 2 bonds, tolerates a wide range of allylic and homoallylic alcohols, and acrylates (see scheme; TIPS =triisopropylsilyl). The methodology was applied to the synthesis of the C13-C21 fragment of palmerolide A.
Rhodium-catalyzed reaction of 1-alkenylboronates with aldehydes leading to allylation products
Shimizu, Hiroshi,Igarashi, Tomohiro,Miura, Tomoya,Murakami, Masahiro
supporting information; experimental part, p. 11465 - 11469 (2012/01/11)
Synthetic equivalents: 1-Alkenylboronates perform the role of an allylating reagent. Their reaction with aldehydes in the presence of a cationic rhodium(I)/dppm catalyst results in a highly diastereoselective production of anti-configured homoallylic alco
