41860-46-2Relevant articles and documents
A neutral Gold(III)-Boron transmetalation
Hofer, Manuel,Gomez-Bengoa, Enrique,Nevado, Cristina
supporting information, p. 1328 - 1332 (2014/04/17)
The occurrence of direct transmetalation between gold(III) and boron species during gold-catalyzed cross-coupling reactions has recently become the subject of intense discussion. In this work, we investigate the transmetalation reaction between discrete, stable gold(III) complexes and boron reagents. Interestingly, electron-rich arylboronic acids remain unreactive under neutral conditions, whereas electron-deficient species undergo transmetalation in a highly efficient manner.