41997-49-3Relevant articles and documents
Photocatalytic carbanion generation-benzylation of aliphatic aldehydes to secondary alcohols
Donabauer, Karsten,Maity, Mitasree,Berger, Anna Lucia,Huff, Gregory S.,Crespi, Stefano,K?nig, Burkhard
, p. 5162 - 5166 (2019/06/05)
We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO2 extrusion and reduction of the in situ formed radical yields a carbanion capable of reacting with aliphatic aldehydes as electrophiles giving the Grignard analogous reaction product.
Optical resolution of 1,1 diphenyl alkane 2 ols
Haller,Schneider
, p. 846 - 856 (2007/10/12)
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