41998-16-7

Basic information

• Product Name: phenyl 2-chlorobenzoate
• Synonyms: phenyl 2-chlorobenzoate
• CAS NO: 41998-16-7
• Molecular Formula: C₁₃H₉ClO₂
• Molecular Weight: 232.66
• Mol File: 41998-16-7.mol
• Article Data: 11

Chemical Properties

• Melting Point: 180-181 °C
• Boiling Point: 356.3°Cat760mmHg
• Flash Point: 185.1°C
• Appearance: /
• Density: 1.258g/cm³
• Vapor Pressure: 2.95E-05mmHg at 25°C
• Refractive Index: 1.594
• CAS DataBase Reference: phenyl 2-chlorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2-chlorobenzoate(41998-16-7)
• EPA Substance Registry System: phenyl 2-chlorobenzoate(41998-16-7)

Safety Data

• Hazardous Substances Data: 41998-16-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H9ClO2/c14-12-9-5-4-8-11(12)13(15)16-10-6-2-1-3-7-10/h1-9H

Upstream product

• 79-21-0 peracetic acid 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 609-65-4 o-chlorobenzoyl chloride 
• 108-95-2 phenol 
• 118-91-2 ortho-chlorobenzoic acid 
• 106-41-2 4-bromo-phenol 
• 118-55-8 phenyl Salicylate 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 1885-14-9 phenyl chloroformate 
• 89-98-5 2-chloro-benzaldehyde 
• 98-80-6 phenylboronic acid 
• 49619-43-4 2-chlorobenzoic anhydride 
• 100-66-3 methoxybenzene 
• 64-18-6 formic acid 

Downstream Products

• 55270-71-8 (4-hydroxyphenyl)-(2-chlorophenyl)-methanone 
• 17849-38-6 2-Chlorobenzyl alcohol 
• 41997-74-4 2-Benzenesulfonyl-1-(2-chloro-phenyl)-2-methoxy-ethanone 
• 41997-83-5 1-(2-Chloro-phenyl)-2-methoxy-2-(toluene-4-sulfonyl)-ethanone 
• 118-91-2 ortho-chlorobenzoic acid 
• 108-95-2 phenol 
• 41998-01-0 C₁₈H₁₉ClO₅S 
• 41998-02-1 C₁₈H₁₉ClO₅S 
• 14367-94-3 1-(2-chlorophenyl)-2-nitroethan-1-one 
• 7335-25-3 ethyl 2-chlorobenzoate 
• 1456616-35-5 C₁₂H₁₀ClNO₃ 

Relevant articles and documents

Palladium-catalyzed alkoxycarbonylation of aryl halides with phenols employing formic acid as the CO source

An efficient palladium-catalyzed alkoxycarbonylation of aryl halides with phenols has been developed. Various aryl benzoates have been isolated in good to excellent yields with formic acid as the CO source. The reaction proceeds smoothly under mild conditions and good functional group tolerance was observed.

Ligand-free palladium-catalyzed aerobic oxidative coupling of carboxylic anhydrides with arylboronic acids

We report a new, effective and environmentally friendly protocol for selective aerobic oxidative coupling of arylboronic acids with carboxylic anhydrides in the presence of ligand-free palladium catalyst. The aryl benzoates are obtained in good to excellent yields.

Palladium-catalyzed aerobic oxidative coupling of acyl chlorides with arylboronic acids

The first example of a palladium-catalyzed aerobic oxidative coupling of acyl chlorides with arylboronic acids has been developed, leading to a wide range of aryl benzoates in good to excellent yields. This catalytic system shows broad functional group tolerance. Preliminary mechanistic experiments using deuterium labeling showed that the oxygen atom was derived from dioxygen. Copyright