420088-66-0Relevant articles and documents
Biomimetic hydroxylation of saturated carbons with artificial cytochrome P-450 enzymes - Liberating chemistry from the tyranny of functional groups
Breslow, Ronald,Yang, Jerry,Yan, Jiaming
, p. 653 - 659 (2002)
Five mimics of cytochrome P-450 have been prepared and examined as catalysts for the specific hydroxylation of steroids. Reactions occur dictated by the geometries of the complexes, overcoming the intrinsic reactivity of a carbon-carbon double bond and of