42198-68-5

Basic information

• Product Name: α-deuteriocinnamic acid
• Synonyms: α-deuteriocinnamic acid
• CAS NO: 42198-68-5
• Molecular Weight: 149.153
• Mol File: 42198-68-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: α-deuteriocinnamic acid(CAS DataBase Reference)
• NIST Chemistry Reference: α-deuteriocinnamic acid(42198-68-5)
• EPA Substance Registry System: α-deuteriocinnamic acid(42198-68-5)

Safety Data

• Hazardous Substances Data: 42198-68-5(Hazardous Substances Data)

Upstream product

• 122570-52-9 (2-carboxy-1-phenylethenyl-2-d)tris(3-sulfophenyl)phosphonium inner salt, trisodium salt 
• 140-10-3 cis-cinnamic acid 
• 100-52-7 benzaldehyde 
• 21788-36-3 (Z)-methyl 2-bromo-3-phenylacrylate 
• 55836-65-2 methyl (α-deuterio)cinnamate 
• 4610-69-9 (Z)-ethyl cinnamate 

Downstream Products

• 1279102-35-0 α-D-(E)-cinnamoyl fluoride 
• 370558-37-5 N-(2-iodo-4-methylphenyl)-N-benzyl-(α-deuterio)cinnamide 
• 370558-28-4 3-hydroxy-1,3-dibenzyl-5-methylindolin-2-one 
• 370558-21-7 1,3-dibenzyl-5-methylindolin-2-one 
• 473469-85-1 C₂₀H₁₅⁽²⁾HO₄ 
• 30833-66-0 2-deuterio-2-oxo-acetic acid 
• 100-52-7 benzaldehyde 
• 81509-22-0 acide<²H>-2 phenyl-3 endo bicyclo<2.2.1> heptene-5 carboxylique-2 exo<²H> 
• 81509-22-0 acide<²H>-2 phenyl-3 exo bicyclo<2.2.1> heptene-5 carboxylique-2 endo <²H> 

Relevant articles and documents

Mechanism leading to the observed product of intramolecular aryl Diels-Alder reaction

A mechanistic investigation into the recently reported intramolecular aryl Diels-Alder reaction was carried out using deuterium labeling. These studies led to the conclusion that the initial Diels-Alder adduct is isomerized to a highly conjugated tetra-ene intermediate which undergoes a stereospecific suprafacial 1,5-dienyl hydrogen shift to give the observed product.

Regioselective Hydrometalation of Alkenes Reveals the Amphipolar Nature of the Pd-H Bond in Heterogeneous Hydrogenation

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Vinyl Anions. Part 9. Vinyl Carbanions Derived from Acrylic Esters and their β-Phenyl Derivatives

Ethyl ββ-diphenylacrylate, ethyl cis- and trans-cinnamate, methyl and ethyl maleate, ethyl fumarate, and methyl acrylate were treated with a strong base at low temperatures to yield the derived vinyl carbanions.The vinyl carbanions were treated with vario