422268-02-8Relevant articles and documents
Concise synthesis of tetrahydropyrans by a tandem oxa-michael/tsuji-trost reaction
Wang, Liang,Li, Pengfei,Menche, Dirk
supporting information; experimental part, p. 9270 - 9273 (2011/02/28)
A novel domino sequence facilitates the rapid assembly of polysubstituted tetrahydropyrans. The one-pot relay process generates up to three new stereogenic centers, including a tetrasubstituted carbon center, in a highly concise and convergent fashion from simple starting materials. Copyright
Synthesis of homoallylic alcohols via lewis acid assisted enantioselective desymmetrization
Yu, Bing,Menard, Frederic,Isono, Naohiro,Lautens, Mark
experimental part, p. 853 - 859 (2009/08/16)
A highly enantioselective allylic substitution of (Z)-but-2-ene-1,4-diol derivatives was developed using a rhodium(I) catalyst and arylboronic acids as nucleophiles. The reaction yields versatile homoallylic alcohols from readily available linear biscarbonates. Georg Thieme Verlag Stuttgart.