42370-41-2

Basic information

• Product Name: TRANS-SOBREROL
• Synonyms: TRANS-5-HYDROXY-ALPHA,ALPHA,4-TRIMETHYL-3-CYCLOHEXENE-1-METHANOL;TRANS-SOBREROL;TRANS-P-MENTH-1-ENE-6,8-DIOL;TRANS-P-MENTH-6-ENE-2,8-DIOL;trans-5-hydroxy-alpha,alpha,4-trimethylcyclohex-3-ene-1-methanol;trans-5-Hydroxy-α,α,4-trimethyl-3-cyclohexene-1-methanol;Einecs 255-780-7;trans-5-Hydroxy-alpha,alpha,4-trimethyl-3-cyclohexene-1-methanol trans-p-Menth-1-ene-6,8-diol
• CAS NO: 42370-41-2
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.25
• EINECS: 255-780-7
• Product Categories: Biochemistry;Monocyclic Monoterpenes;Terpenes
• Mol File: 42370-41-2.mol
• Article Data: 8

Chemical Properties

• Melting Point: 130-132 °C(lit.)
• Boiling Point: 270-271 °C(lit.)
• Flash Point: 213.3oC
• Appearance: /
• Vapor Pressure: 1.67E-11mmHg at 25°C
• CAS DataBase Reference: TRANS-SOBREROL(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-SOBREROL(42370-41-2)
• EPA Substance Registry System: TRANS-SOBREROL(42370-41-2)

Safety Data

• WGK Germany: 3
• RTECS: FI2000000
• Hazardous Substances Data: 42370-41-2(Hazardous Substances Data)

Usage

General Description

Trans-Sobrerol is a synthetic chemical compound belonging to the class of cyclic terpene alcohols, known for its potent antioxidant and anti-inflammatory properties. It is commonly used in pharmaceutical and cosmetic products for its ability to protect cells from oxidative stress and reduce inflammation. Trans-Sobrerol has also been studied for its potential therapeutic applications in treating conditions such as arthritis, diabetes, and cardiovascular diseases. This chemical has shown promising effects in protecting against free radical damage and in modulating immune responses, making it a valuable ingredient in various health and beauty products.

InChI:InChI=1/2C10H18O2/c2*1-7-4-5-8(6-9(7)11)10(2,3)12/h2*4,8-9,11-12H,5-6H2,1-3H3/t2*8-,9+/m10/s1

Upstream product

• 58506-22-2 p-menthane-1,2,8-triol 
• 80-56-8 rac-α-pinene 
• 60661-95-2 1,6-dichloro-p-menthane-2,8-diol 
• 80-56-8 Pinene 
• 99-49-0 Carvone 
• 1686-14-2 α-pinene epoxide 
• 110202-13-6 1,2-dibromo-p-menthan-8-ol 
• 98-55-5 terpineol 
• 1686-14-2 (1R,2R,4S,6R)-2,7,7-trimethyl-3-oxatricyclo[4.1.1.0.^2,4]octane 
• 1197-06-4 cis-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-ol 
• 80-26-2 terpinyl acetate 
• 56423-45-1 (4R,8RS)-8,9-epoxy-p-menth-6-en-2-one 
• 772-36-1 (1R,5R)-5-(2-hydroxypropan-2-yl)-2-methylcyclohex-2-enol 
• 71697-84-2 (-)-trans-sobrerol 

Downstream Products

• 68754-15-4 6,8-diacetoxy-p-menth-1-ene 
• 38235-58-4 trans-sobrerol 
• 137821-91-1 (-)-(1S,5R)-sobrerol 
• 106262-55-9 Octanoic acid 5-(1-hydroxy-1-methyl-ethyl)-2-methyl-cyclohex-2-enyl ester 
• 71697-84-2 (-)-trans-sobrerol 
• 38223-90-4 p-menthane-1,2,6,8-tetraol 
• 7712-46-1 5-(1-Hydroxy-1-methyl-ethyl)-2-methyl-cyclohex-2-enone 

Relevant articles and documents

Biomimetic conversion of α-pinene with H2O2 to sobrerol over V2O5: Dihydroxylation by a peroxo vanadium peracid vectoring gentle synergistic oxidation

In this communication, we report the gentle preparation of sobrerol from dihydroxylation of α-pinene synergistically catalyzed by V2O5-H2O2 under benign conditions. It was proposed that a “peroxo vanadium acid”, VVO(OH)(OOH), was formed by HOO? insertion and proton transfer between V2O5 and H2O2. Theoretical DFT calculations that using the dimer?vanadium peracid as a model of the catalytically active species revealed that peroxo vanadium acid exhibited bifunctional catalytic capabilities resembling epoxidation of α-pinene by peracetic acid and then open-ring hydration with an acetic media.

Unique salt effect on highly selective synthesis of acid-labile terpene and styrene oxides with a tungsten/Hcatalytic system under acidic aqueous conditions

Acid-labile epoxides such as terpene and styrene oxides are effectively synthesized in high yields with good selectivities using tungsten-catalyzed hydrogen peroxide epoxidation in the presence of NaO The salt effect is thought to originate with the addition of a saturated amount of NaOto aqueous H this addition strongly inhibited the undesired hydrolysis of the acid-labile epoxy products, despite the biphasic conditions of substrate as oil phase and Has acidic aqueous phase.

Comparative autoxidation of 3-Carene and α-Pinene: Factors governing regioselective hydrogen abstraction reactions

Autoxidation reactions of 3-Carene 1 and α-Pinene 2 were performed using various homogeneous catalysts. Different product and regio- selectivities were observed. The factors that promote hydrogen abstraction (HA) reactions in both molecules are discussed, and it is proposed that the difference in the product selectivities is due to the lack of 'cyclic activation' in 2. Oxidation of 1 produced mainly 3-carene-5-one 3, while 2 yielded 2,3-epoxypinane 6 as the major product.