425-23-0

Basic information

• Product Name: isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate
• Synonyms: isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate
• CAS NO: 425-23-0
• Molecular Weight: 256.12
• Mol File: 425-23-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate(425-23-0)
• EPA Substance Registry System: isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate(425-23-0)

Safety Data

• Hazardous Substances Data: 425-23-0(Hazardous Substances Data)

Upstream product

• 375-22-4 heptafluorobutyric Acid 
• 74-98-6 propane 
• 201230-82-2 carbon monoxide 

Downstream Products

• 375-01-9 2,2,3,3,4,4,4-heptafluorobutanol 

Relevant articles and documents

Homogeneous oxidation of alkanes: Role of rhodium–alkyl complexes

Catalytic systems RhCl3–KI–NaCl and RhCl3–Cu(OAcf)2–NaCl in aqueous perfluorinated carboxylic acids (CF3COOH, C3F7COOH) are effective in coupled oxidation of alkanes and carbon monoxide with dioxygen. In their presence, predominant is the outer-sphere oxidation of alkanes into respective esters (alcohols) with involvement of peroxo rhodium species as an oxidant (mechanism A). The process occurs partially by the inner-sphere mechanism B involving Rh–alkyl intermediates. Mechanism B is supported by (a) formation of alkyl chlorides, (b) synthesis of acetic acid in conversion of methane, and (c) positional selectivity in oxidation of propane.