4250-46-8Relevant articles and documents
Substituent Effects in the Cyclization of Yne-Diols Catalyzed by Gold Complexes Featuring L2/Z-Type Diphosphinoborane Ligands
Inagaki, Fuyuhiko,Nakazawa, Kenta,Maeda, Kakeru,Koseki, Tomoya,Mukai, Chisato
supporting information, p. 3005 - 3008 (2017/09/05)
Gold(I) complexes featuring Z-type ligands introducing electron-withdrawing groups (EWG), Au(DPBF)Cl (4a) and Au(DPBCl)Cl (4b) (DPB = diphosphine-boron), have been synthesized and structurally characterized. These studies suggest tha
Regioselective electrophilic borylation of haloarenes
Del Grosso, Alessandro,Ayuso Carrillo, Josue,Ingleson, Michael J.
supporting information, p. 2878 - 2881 (2015/02/19)
Haloarenes undergo direct borylation using amine:BCl3:AlCl3 in the ratio of 1:1:2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.