42548-90-3Relevant articles and documents
Synthesis of Allylic Alcohols via Palladium-Catalyzed Cross-Coupling of Vinylic Epoxides and Aryl or Vinylic Halides and Triflates
Larock, Richard C.,Ding, Shuji
, p. 804 - 806 (1993)
Palladium acetate in the presence of sodium formate, n-Bu4NCl, and diisopropylethylamine catalyzes the cross-coupling of vinylic epoxides with aryl or vinylic halides and triflates to form allylic alcohols in good yield.
Synthesis and biological activity of permethrinic acid analogs containing various substituents in position 2 of the cyclopropane ring
Mirzabekova,Kuz'mina,Lukashov,Sokolova,Golosov,Kazakov,Perlova,Potapova,Kheinman,Ivanova
experimental part, p. 1139 - 1149 (2009/09/25)
A number of permethrinic acid ethyl ester derivatives having various substituents [Et, Pr, Ph, Ph(CH2) n (n = 1, 2), etc.] in position 2 of the cyclopropane ring were synthesized, and their insecticidal acivity against typhoid flies, rice weevils, and bean aphides, as well as juvenoid activity on flour beetle chrysalises, was studied. The newly synthesized compounds turned out to exhibit weak insecticidal activity against standard insects but pronounced juvenile hormone activity, which differentiates them from permethrinic acid esters.
SYNTHESIS OF ALLYLIC ALCOHOLS VIA ORGANOPALLADIUM ADDITIONS TO UNSATURATED EPOXIDES
Larock, Richard C.,Ilkka, Steven J.
, p. 2211 - 2214 (2007/10/02)
The reaction of aryl- and vinylpalladium compounds with vinylic and allylic epoxides provides an excellent, high yielding, regio- and stereoselective route to functionally substituted allylic alcohols which can be made catalytic in palladium.
