425686-45-9

Basic information

• Product Name: methyl 3-(2-hydroxyphenyl)propiolate
• Synonyms: methyl 3-(2-hydroxyphenyl)propiolate
• CAS NO: 425686-45-9
• Molecular Weight: 176.172
• Mol File: 425686-45-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 3-(2-hydroxyphenyl)propiolate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(2-hydroxyphenyl)propiolate(425686-45-9)
• EPA Substance Registry System: methyl 3-(2-hydroxyphenyl)propiolate(425686-45-9)

Safety Data

• Hazardous Substances Data: 425686-45-9(Hazardous Substances Data)

Upstream product

• 533-58-4 2-Iodophenol 
• 1002130-71-3 methyl 3-[2-(methoxymethoxy)phenyl]propiolate 

Downstream Products

• 20280-81-3 4-methoxycoumarin 
• 15185-05-4 4-phenylcoumarin 
• 132018-11-2 3-(methoxycarbonyl)-2-(4-nitrophenyl)-4H-benzopyran-4-one 
• 132018-07-6 2-(4-bromophenyl)-3-(methoxycarbonyl)-4H-benzopyran-4-one 
• 1391042-55-9 methyl 2-(4-chlorophenyl)-4-oxo-4H-chromene-3-carboxylate 
• 1391042-54-8 methyl 2-(4-fluorophenyl)-4-oxo-4H-chromene-3-carboxylate 
• 78589-68-1 methyl 4-oxo-2-phenyl-4H-chromene-3-carboxylate 
• 1391042-49-1 methyl 4-oxo-2-(p-tolyl)-4H-chromene-3-carboxylate 
• 1417564-53-4 methyl 4-hydroxy-2-(4-nitrophenyl)-2H-chromene-3-carboxylate 

Relevant articles and documents

Studies toward the Total Synthesis of Arylnaphthalene Lignans via a Photo-Dehydro-Diels-Alder (PDDA) Reaction

An efficient method for the preparation of arylnaphthalene lignans (ANLs) was developed, which is based on the Photo-Dehydro-Diels-Alder (PDDA) reaction. While intermolecular PDDA reactions turned out to be inefficient, the intramolecular variant using suberic acid as tether linking two aryl propiolic esters smoothly provided naphthalenophanes. The irradiations were performed with a previously developed annular continuous-flow reactor and UVB lamps. In this way, the natural products Alashinol D, Taiwanin C, and an unnamed ANL could be prepared.