42580-44-9

Basic information

• Product Name: Benzaldehyde, 4-amino-3-bromo-
• CAS NO: 42580-44-9
• Molecular Formula: C7H6BrNO
• Molecular Weight: 200.035
• Mol File: 42580-44-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 4-amino-3-bromo-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-amino-3-bromo-(42580-44-9)
• EPA Substance Registry System: Benzaldehyde, 4-amino-3-bromo-(42580-44-9)

Safety Data

• Hazardous Substances Data: 42580-44-9(Hazardous Substances Data)

Upstream product

• 21128-88-1 chloromethyl methyl sulfoxide 
• 615-36-1 2-bromoaniline 
• 556-18-3 4-aminobenzaldehyde 
• 67-68-5 dimethyl sulfoxide 
• 583-68-6 2-bromo-p-toluidine 

Downstream Products

• 371765-80-9 2-bromo-4-(((4-cyanobenzyl)oxy)(1-methyl-1H-imidazol-5-yl)methyl)benzonitrile 
• 371765-79-6 2-bromo-4-(hydroxy(1-methyl-1H-imidazol-5-yl)methyl)benzonitrile 
• 89891-70-3 2-bromo-4-formylbenzonitrile 
• 820976-77-0 trans-3-{2-[5-(4-methanesulfonylpiperazin-1-ylmethyl)-2-nitrophenyl]vinyl}-2-methoxyquinoline 
• 850171-04-9 2-bromo-4-(4-methanesulfonylpiperazin-1-ylmethyl)aniline 

Relevant articles and documents

Regiospecific oxidation of an alkyl group of aromatic amine to carbonyl group by DDQ in aq. medium

The regiospecific oxidation of alkyl group of both sterically hindered and unhindered aromatic amine to corresponding carbonyl compound was done in aq. medium by using DDQ. The optimized reaction protocol was found to be most simple, high yielding and novel method for oxidation of alkyl group of aromatic amine in to its carbonyl compound.

Simple Synthetic Route to 4-Aminobenzaldehydes from Anilines

Anilines unsubstituted at the 4-position react under mild conditions in Me2SO-HCl solvent (H+ = 0.6 mol dm-3) to give substituted 4-aminobenzaldehydes in high yields; although addition of CuCl2 gives a cleaner product, it is not esse