42758-92-9

Basic information

• Product Name: 9-(N,N-diMethylaMinoMethyl)anthracene
• Synonyms: 9-(N,N-diMethylaMinoMethyl)anthracene;N,N-dimethyl-9-Anthracenemethanamine
• CAS NO: 42758-92-9
• Molecular Formula: C₁₇H₁₇N
• Molecular Weight: 235.32358
• Mol File: 42758-92-9.mol
• Article Data: 4

Chemical Properties

• Melting Point: 75-77 °C(Solv: ethanol (64-17-5))
• Boiling Point: 375.8±11.0 °C(Predicted)
• Appearance: /
• Density: 1.098±0.06 g/cm3(Predicted)
• PKA: 8.80±0.28(Predicted)
• CAS DataBase Reference: 9-(N,N-diMethylaMinoMethyl)anthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(N,N-diMethylaMinoMethyl)anthracene(42758-92-9)
• EPA Substance Registry System: 9-(N,N-diMethylaMinoMethyl)anthracene(42758-92-9)

Safety Data

• Hazardous Substances Data: 42758-92-9(Hazardous Substances Data)

Upstream product

• 68-12-2 N,N-dimethyl-formamide 
• 642-31-9 9-anthracene aldehyde 
• 506-59-2 N,N-dimethylammonium chloride 

Downstream Products

• 851537-25-2 (anthracen-9-ylmethyl)(triphenyl)phosphonium iodide 
• 55614-27-2 5,6,11,12-tetrahydro-4b,12<1',2'>:6,10b<1,2>-dibenzenochrysene 
• 17277-99-5 1,2,7,8-tetrahydro-2a,7[1',2']:8,12b[1'',2'']-dibezenodibenzo[a,e]cyclobuta[c]cyclooctene 
• 84-65-1 9,10-phenanthrenequinone 

Relevant articles and documents

Unsymmetrical photodimerization of a 9-aminomethylanthracene in the crystalline salt

By the salt formation with particular nonaromatic dicarboxylic acids, rapid and selective photodimerization of 9-(N,N-dimethylaminomethyl)anthracene (1) was accomplished in the solid state. For instance, the salt with trans,trans-muconic acid or acetylenedicarboxylic acid was led quantitatively to the 9,10:4′,1′ photodimer usy-ht-2, the first example of the unsymmetrical [4+4] photodimerization of anthracene in the solid state. The reactions were rationalized by the relevant C...C distances between the reacting carbons.

Palladium-Catalyzed Highly Regioselective Aromatic Substitution of Benzylic Ammonium Salts with Amines

An unprecedented aromatic substitution reaction of benzylic ammonium salts has been developed through palladium-catalyzed C-N bond cleavage. A range of primary and secondary amines participated in a palladium-catalyzed aromatic substitution reaction of benzylic ammonium salts, delivering sterically hindered aromatic amines in moderate to excellent yields with extremely high regioselectivity. Preliminary mechanistic studies permitted successful identification of Π-benzylpalladium complexes and Γ-vinyl allylic amines as key intermediates. This study paves the way for the use of benzylic ammonium salts in the aromatic substitution reactions.