4281-21-4Relevant articles and documents
Photochemistry of o-Phthalaldehyde
Scaiano, Juan C.,Encinas, M. Victoria,George, Manapurathu V.,Williams, D. Lyn H.
, p. 724 - 730 (1980)
U.v.-irradiation of o-phthalaldehyde leads to the formation of phthalide and dimeric products in varying yields and ratios depending on the solvent and reagent concentration.Laser flash photolysis studies show that the photochemistry of o-phthalaldehyde involves the intermediacy of a 1,4-biradical produced by intramolecular hydrogen transfer, and with a lifetime of 1.6 μs.Two triplet states are the precursors of the biradical; they have lifetimes of 6 and 36 ns and are assigned to different rotational conformers.The triplet reaction path is not responsible for product formation; these arise via a parallel reaction path, apparently involving the singlet state.
Central nervous system active compounds. IV. Synthesis of 3-aminobenzylphthalides
Hutchison,Marshall,Prager,et al.
, p. 2699 - 2715 (2007/10/02)
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