43017-99-8Relevant articles and documents
D-A type near-infrared organic light-emitting material as well as preparation method and application thereof
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Paragraph 0053; 0057-0059, (2020/09/10)
The invention relates to a D-A type near-infrared organic light-emitting material and a preparation method and application thereof. Naphthothiazole quinoxaline is introduced in a closed-loop mode to serve as a rigid large-plane electron acceptor structure. A strong electron donor structure with a high HOMO energy level is selected, and the intermolecular torque is enhanced through the change of aconnection position, so that the separation of the HOMO/LUMO energy level is effectively enhanced. The invention provides a series of D-A type near-infrared organic light-emitting materials containingnaphthothiazole quinoxaline structural units. The raw materials are easy to obtain, the preparation process is simple, the reaction process is easy to control, and the product is easy to separate, high in yield and high in purity; the material shows good thermal stability, and film state luminescence is in a near-infrared region; and important application potential is shown in the aspect of near-infrared organic light-emitting devices.
Organic light-emitting material, application of organic light-emitting material and organic light-emitting device
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Paragraph 0066-0067; 0069, (2018/09/11)
The invention relates to an organic light-emitting material, application of the organic light-emitting material and an organic light-emitting device. The organic light-emitting material comprises a compound shown in the following general formula (1), which is shown in the description. In the general formula (1), Y1 and Y2 are respectively selected from one of hydrogen group and cyano group; X1 andX2 are respectively selected from one of CH or N; L1 is connected with one or two R1, L2 is connected with one or two R2, and L1 and L2 are respectively selected from hydrogen group or single bond, and/or aryl group/hetero aromatic ring with the annular atoms of 6 to 18; R1 and R2 are respectively selected from arylamine group with the annular atoms of 10 to 40. The organic light-emitting material adopts acenaphtho-pyrazine derivative as the structure general formula, and through modifying other different chemical groups, the organic light-emitting material has excellent luminescence characteristics, stable structure and higher colour purity, meanwhile, the preparation cost is relatively low.
Fluorinated 1,8-naphthalimides: Synthesis, solid structure and properties
Huang, Jie,Wu, Di,Ge, Hao-Jie,Liu, Sheng-Hua,Yin, Jun
, p. 1399 - 1402 (2015/02/19)
Three fluorinated 1,8-napthalimides were synthesized from acenaphthene. Their structures were characterized by NMR and EI-MS analyses. The structures of compounds 1b and 1c were also confirmed by X-ray diffraction analysis, which showed that they possessed different packing models. Their optoelectronic properties were investigated. The results indicated that all of the naphthalimides possess good solubility and low LUMO energy level, which make them good solution processing candidates in n-type semiconductor.