4308-55-8Relevant articles and documents
The direct synthesis of isoflavans VIA α-alkylation of phenylacetates
Versteeg, Marietjie,Bezuidenhoudt, Barend C. B.,Ferreira, Daneel
, p. 1373 - 1394 (2007/10/03)
Deprotonation of oxygenated phenylacetates and quenching of the enolates with oxygenated benzylic electrophiles, afforded 2,3-diarylpropanoates which served as precursors to the isoflavans following consecutive reduction and cyclization steps.
TRANSFORMATION DU CATION ISOFLAVYLIUM EN PHENYL-3 COUMARINES, ISOFLAVENES-3 ET ISOFLAVANNES
Deschamps-Vallet, Colette,Ilotse, Jean-Baptiste,Meyer-Dayan, Michele
, p. 3993 - 3996 (2007/10/02)
Isoflavylium salts 1 are key starting materials for synthesis of 3-phenyl coumarins 2,isoflav-3-enes 4 and isoflavans 5, by chemical conversions narrowsly apparented to biogenetic pathways actually recognized for natural compounds of these series.