4316-53-4

Basic information

• Product Name: 4-Methyltriphenylamine
• Synonyms: 4—METHYLTRIPHENYLAMINE;4-Tolyldiphenylamine;4-METHYLTRIPHENYLAMINE,98.0+%(GC);N,N-Diphenyl-p-toluidine;N-(4-Methylphenyl)diphenylamine;Diphenyl p-tolylamine;Diphenyl(4-methylphenyl)amine;Diphenyl(p-methylphenyl)amine
• CAS NO: 4316-53-4
• Molecular Formula: C₁₉H₁₇N
• Molecular Weight: 259.34
• EINECS: 1533716-785-6
• Product Categories: electronic;Acid Anhydrides, etc. (Reagents for Conducting Polymer Research);Functional Materials;Reagents for Conducting Polymer Research
• Mol File: 4316-53-4.mol
• Article Data: 85

Chemical Properties

• Melting Point: 67 °C
• Boiling Point: 393.8 °C at 760 mmHg
• Flash Point: 171.8 °C
• Appearance: /
• Density: 1.095 g/cm³
• Vapor Pressure: 2.08E-06mmHg at 25°C
• Refractive Index: 1.636
• Solubility: soluble in Toluene
• PKA: -2.62±0.30(Predicted)
• CAS DataBase Reference: 4-Methyltriphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methyltriphenylamine(4316-53-4)
• EPA Substance Registry System: 4-Methyltriphenylamine(4316-53-4)

Safety Data

• Hazardous Substances Data: 4316-53-4(Hazardous Substances Data)

Usage

Description

4-Methyltriphenylamine, with the CAS number 4316-53-4, is an organic compound that belongs to the triphenylamine family. It is characterized by its molecular structure, which consists of a central nitrogen atom bonded to three phenyl rings, with one of the phenyl rings having a methyl group attached to it. 4-Methyltriphenylamine is known for its reactivity and versatility in various organic reactions and synthesis processes.

Uses

Used in Organic Synthesis:
4-Methyltriphenylamine is used as a reactant and reagent in organic synthesis for its ability to participate in a wide range of chemical reactions. Its unique structure allows it to act as a building block for the creation of more complex organic molecules, which can be utilized in various applications across different industries.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4-Methyltriphenylamine is used as a reactant for the synthesis of various drug molecules. Its reactivity and structural properties make it a valuable component in the development of new medications, potentially contributing to the treatment of various diseases and health conditions.
Used in Chemical Research:
4-Methyltriphenylamine is also used in chemical research as a reagent for studying the properties and behavior of organic compounds. Its involvement in various chemical reactions provides valuable insights into the mechanisms and pathways of organic synthesis, which can be applied to the development of new materials and technologies.
Used in Material Science:
In the field of material science, 4-Methyltriphenylamine can be used as a component in the development of advanced materials with specific properties. Its incorporation into the molecular structure of these materials can lead to enhanced performance characteristics, such as improved conductivity, stability, or reactivity, depending on the desired application.

InChI:InChI=1/C19H17N/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3

Upstream product

• 624-31-7 4-tolyl iodide 
• 122-39-4 diphenylamine 
• 591-50-4 iodobenzene 
• 591-17-3 meta-bromotoluene 
• 106-38-7 para-bromotoluene 
• 99-99-0 1-methyl-4-nitrobenzene 
• 106-43-4 para-chlorotoluene 
• 106-49-0 p-toluidine 
• 108-86-1 bromobenzene 
• 62-53-3 aniline 
• 1821-36-9 N-phenyl-2-cyclohexylamine 
• 1132-38-3 N-cyclohexylidenebenzenamine 
• 12775-96-1 copper 
• 95-50-1 1,2-dichloro-benzene 

Downstream Products

• 100308-67-6 4,4′-dibromo-4′′-methyltriphenylamine 
• 20441-06-9 N,N'-di(4''-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine 
• 404825-34-9 N,N-di(4-iodophenyl)-4-tolylamine 
• 183994-94-7 4-(N,N-diphenylamino)benzyl bromide 
• 122112-54-3 4-[(4-formylphenyl)(4-methylphenyl)amino]benzaldehyde 
• 89115-21-9 4-(N-(4-methylphenyl)-N-phenylamino)benzaldehyde 
• 1233934-04-7 4-methyl-N,N-bis(4-(9-(3,4,5-trifluorophenyl)-9H-fluoren-9-yl)phenyl)aniline 
• 1233933-99-7 4-methyl-N,N-bis(4-(9-(4-fluorophenyl)-9H-fluoren-9-yl)phenyl)aniline 
• 1235971-60-4 4-methyl-N,N-bis-(4-(9-p-tolyl-9H-fluoren-9-yl)phenyl)aniline 
• 1235971-59-1 4-methyl-N,N-bis-(4-(9-(naphthalen-1-yl)-9H-fluoren-9-yl)phenyl)aniline 
• 1233934-00-3 4-methyl-N,N-bis-(4-(9-(4-tert-butylphen-yl)-9H-fluoren-9-yl)phenyl)aniline 
• 1233934-02-5 4-methyl-N,N-bis(4-(9-(4-(trifluoromethyl)-phenyl)-9H-fluoren-9-yl)phenyl)aniline 
• 1233934-01-4 4-methyl-N,N-bis(4-(2,7-dibromo-9-p-tolyl-9H-fluoren-9-yl)phenyl)aniline 
• 100803-48-3 N,N-bis[4-(2,2-diphenylethenyl)phenyl]-4-methylaniline 

Relevant articles and documents

A copper(ii) complex as an intermediate of copper(i)-catalyzed C-N cross coupling of N-phenylaniline with aryl halide by in situ ESI-MS study

Complexes [Cu(NPh2)2]-, [Cu(NPh 2)I]- and K[Cu(phen)(NPh2) (p-tolyl)] + were observed by in situ electrospray ionization mass spectrometry (ESI-MS) analysis of the copper(i)-cata

DIARYL AMINE COMPOUND AND METHOD FOR PRODUCING THE SAME

The present invention relates to a process for the preparation of diaryl amine compounds. A compound represented by chemical formula 1, a compound represented by chemical formula 2, and a synthetic reagent in a solvent, the synthetic reagent being CsF, KF, 18 - crown -6, K. 2 CO3, [TBAT] The present invention relates to a process for the preparation of diaryl amine compounds comprising a material selected from the group consisting of a (tetrabutylammonium difluorotriphenylsilicate), TBAF (tetrabutylammonium fluoride) and combinations thereof. Chemical Formula 1. Chemical Formula 2. The diaryl amine compound can be synthesized under the absence of a transition metal to be used to synthesize diaryl amine compounds having various substituents.

A Tetraarylpyrrole-Based Phosphine Ligand for the Palladium-Catalyzed Amination of Aryl Chlorides

A tetraarylpyrrole-based phosphine ligand L1 in combination with Pd(dba)2 provided a catalyst for the Buchwald-Hartwig amination reaction. A variety of amines were rapidly coupled with aryl chlorides at a Pd loading of 0.5 mol%. The selective monoarylation of aliphatic primary amines was achieved in the presence of 0.8 equiv. water. Comparison experiments were also conducted, which revealed that the catalytic activity of L1 is superior to representative phosphine ligands in the Pd-catalyzed C?N coupling of various amines. (Figure presented.).

Transition-Metal-Free Diarylation of Isocyanates with Arynes

A facile method for the transition-metal-free diarylation of isocyanates with arynes in the presence of cesium fluoride has been developed, which affords functionalized diaryl amines in moderate to excellent yields. This reaction has good functional group tolerance and provides excellent regioselectivity by utilizing a methoxy-substituted aryne precursor.