4316-58-9Relevant articles and documents
The Reaction of 2,3-Diazabicyclooct-2-ene with Stable Cation Radical Salts
Engel, Paul S.,Hoque, A. K. M. M.,Scholz, John N.,Shine, Henry J.,Whitmire, Kenton H.
, p. 7880 - 7882 (1988)
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Enhanced Electron Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analogue
Vardhaman, Anil Kumar,Lee, Yong-Min,Jung, Jieun,Ohkubo, Kei,Nam, Wonwoo,Fukuzumi, Shunichi
, p. 3709 - 3713 (2016)
Reactions of N,N-dimethylaniline (DMA) with nonheme iron(IV)-oxo and iron(IV)-tosylimido complexes occur via different mechanisms, such as an N-demethylation of DMA by a nonheme iron(IV)-oxo complex or an electron transfer dimerization of DMA by a nonheme iron(IV)-tosylimido complex. The change in the reaction mechanism results from the greatly enhanced electron transfer reactivity of the iron(IV)-tosylimido complex, such as the much more positive one-electron reduction potential and the smaller reorganization energy during electron transfer, as compared to the electron transfer properties of the corresponding iron(IV)-oxo complex.
Synthesis and chemosensory properties of triphenylamine-substituted conjugated polyfluorene containing a terminal di(2-picolyl)amine moiety
Yang, Po-Chih,Wen, Hua-Wen,He, Hsiao-Jou
, p. 101826 - 101833 (2015)
This paper describes the synthesis of a triphenylamine-substituted alternating conjugated polyfluorene (PFAD) containing a pendant terminal di(2-picolyl)amine (DPA) group through the Heck coupling reaction. We examined the effect of DPA units on the senso
Synthesis and optoelectronic properties of thermally cross-linkable hole-transporting poly(fluorene-co-triphenylamine)
Su, Wen-Fen,Chen, Yun
, p. 77 - 85 (2011)
This paper describes the synthesis of a new thermally cross-linkable hole-transporting poly(fluorene-co-triphenylamine) (PFTV) by Suzuki coupling reaction and its application in polymer light-emitting diodes (PLEDs). The characteristics of PFTV were analy
In situ generated tris(p-bromophenyl)amine radical cation promoted electron transfer reaction of cyclopropyl silyl ethers
Hasegawa, Eietsu,Kakinuma, Koji,Yanaki, Tomoyo,Komata, Shota
, p. 10876 - 10881 (2009)
Tris(p-bromophenyl)aminium hexachloroantimonate and perchlorate were utilized to promote the oxidative ring-opening reaction of cyclopropyl silyl ethers giving ring-expanded ketones. Exploration of salt quantity effect on the reaction allowed us to hypoth
Synthetic method of phenylacetonitrile-based aromatic mechanical response fluorescent material
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Paragraph 0050-0053, (2021/03/13)
The invention discloses a synthetic method of a phenylacetonitrile-based aromatic mechanical response fluorescent material, which comprises the following steps: reacting 1 part of brominated intermediate R with 1-4 parts of 4-cyanomethylphenylboronic acid
Phosphoric acid delayed-fluorescence material and preparation method thereof
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Paragraph 0031-0033, (2021/07/28)
The invention relates to the technical field of electroluminescence, in particular to a phosphoric acid delayed-fluorescence material and a preparation method thereof. The phosphoric acid delayed-fluorescent material provided by the invention has a structural formula as shown in a formula (I) which is described in the specification. The invention also provides a preparation method of the phosphoric acid delayed-fluorescence material. The preparation method comprises the following step: subjecting a compound as shown in a formula (II) to reacting with a compound as shown in the formula (III) to prepare the compound as shown in the formula (I). The phosphoric acid delayed-fluorescent material and a preparation method thereof provided by the invention solve the technical problems that existing red TADF materials are relatively difficult to synthesize and device efficiency is not high.
Anthracene-triphenylamine-based platinum(II) metallacages as synthetic light-harvesting assembly
Li, Yanrong,Rajasree, Sreehari Surendran,Lee, Ga Young,Yu, Jierui,Tang, Jian-Hong,Ni, Ruidong,Li, Guigen,Houk, Kendall N.,Deria, Pravas,Stang, Peter J.
supporting information, p. 2908 - 2919 (2021/03/01)
Two trigonal prismatic metallacages 1 and 2 bearing triphenylamine and anthracene moieties are designed and synthesized to fabricate artificial light-harvesting systems (LHSs). These two cages are prepared via the coordination-driven self-assembly of two