432038-16-9

Basic information

• Product Name: 6-benzenesulfinyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydro-2H-pyran
• Synonyms: 6-benzenesulfinyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydro-2H-pyran
• CAS NO: 432038-16-9
• Molecular Weight: 468.805
• Mol File: 432038-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-benzenesulfinyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: 6-benzenesulfinyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydro-2H-pyran(432038-16-9)
• EPA Substance Registry System: 6-benzenesulfinyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydro-2H-pyran(432038-16-9)

Safety Data

• Hazardous Substances Data: 432038-16-9(Hazardous Substances Data)

Downstream Products

• 114275-39-7 (2R,3R,4E)-1,3-benzylidene-4-octadecene-1,2,3-triol 
• 114275-40-0 (2R,3R)-trans-2-azide-1,3-O-benzylidene-1,3-octadec-4-enediol 
• 103348-49-8 2-azido-sphingosine 
• 123-78-4 (2S,3R,4E)-2-amino-4-octadecene-1,3-diol 
• 54336-64-0 (2S,3R,4E)-2-(N-stearoylamino)-4-octadecene-1,3-diol 

Relevant articles and documents

Synthesis of D-erythro-sphingosine and D-erythro-ceramide.

A 1,2-metallate rearrangment of a higher order cuprate derived from an alpha-lithiated xylal derivative and tridecyllithium is the key step in a synthesis of D-erythro-sphingosine and ceramide. A convenient method for preparing alpha-lithiated glycals from alpha-phenylsulfinyl glycals is also described.