4333-75-9

Basic information

• Product Name: 1-p-Anisyl-1-phenylethene
• Synonyms: 1-(4-Methoxyphenyl)-1-phenylethene;1-Methoxy-4-(1-phenylethenyl)benzene;1-p-Anisyl-1-phenylethene;1-Phenyl-1-(4-methoxyphenyl)ethene;α-(4-Methoxyphenyl)styrene;α-Phenyl-4-methoxystyrene
• CAS NO: 4333-75-9
• Molecular Formula: C₁₅H₁₄O
• Molecular Weight: 210.27
• Mol File: 4333-75-9.mol
• Article Data: 130

Chemical Properties

• Boiling Point: 331.2°C at 760 mmHg
• Flash Point: 130.7°C
• Appearance: /
• Density: 1.021g/cm³
• Vapor Pressure: 0.000304mmHg at 25°C
• Refractive Index: 1.563
• CAS DataBase Reference: 1-p-Anisyl-1-phenylethene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-p-Anisyl-1-phenylethene(4333-75-9)
• EPA Substance Registry System: 1-p-Anisyl-1-phenylethene(4333-75-9)

Safety Data

• Hazardous Substances Data: 4333-75-9(Hazardous Substances Data)

Usage

Classification

Derivative of styrene, belongs to the family of phenyl ethenes

Physical state

Colorless liquid at room temperature

Odor

Sweet, floral

Usage

Commonly used in the manufacture of perfumes and fragrances, production of polymers, and as a flavoring agent in the food industry

Safety precautions

May cause skin and eye irritation upon contact, handle with caution

InChI:InChI=1/C15H14O/c1-12(13-6-4-3-5-7-13)14-8-10-15(16-2)11-9-14/h3-11H,1H2,2H3

Upstream product

• 71-23-8 propan-1-ol 
• 611-94-9 4-Methoxybenzophenone 
• 917-64-6 methyl magnesium iodide 
• 60-29-7 diethyl ether 
• 94001-65-7 1-(4-methoxyphenyl)-1-phenylethan-1-ol 
• 64-19-7 acetic acid 
• 100-42-5 styrene 
• 1600-27-7 mercury(II) diacetate 
• 100-66-3 methoxybenzene 
• 17256-00-7 1-(4-hydroxyphenyl)-1-phenylethylene 
• 77-78-1 dimethyl sulfate 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 71897-86-4 (E/Z)-1,3-(4-methoxyphenyl)-1,3-diphenylbut-2-ene 
• 71-43-2 benzene 

Downstream Products

• 17684-11-6 3-(4-anisyl)cinnamic acid 
• 24845-40-7 2-(4-methoxyphenyl)acetophenone 
• 16343-36-5 2-(4-methoxy-phenyl)-2-phenylacetaldehyde 
• 2605-18-7 1-methoxy-4-(1-phenylethyl)benzene 
• 71897-86-4 (E/Z)-1,3-(4-methoxyphenyl)-1,3-diphenylbut-2-ene 
• 211930-12-0 2-hydroxy-2-(4-methoxyphenyl)-2-phenylacetaldehyde 
• 58617-69-9 1-(2,2-difluoro-2-phenylethyl)-4-methoxybenzene 
• 54766-43-7 2-p-Methoxy-phenyl-2-phenyl-vinyliodid 
• 135754-59-5 methyl 2-(4-methoxyphenyl)-2-phenylethyl ether 
• 135754-65-3 C₃₁H₃₂O₃ 

Relevant articles and documents

Photoredox-Catalyzed α-Aminomethyl Carboxylation of Styrenes with Sodium Glycinates: Synthesis of γ-Amino Acids and γ-Lactams

A visible-light photoredox-catalyzed reductive α-aminomethyl carboxylation of styrenes with sodium glycinates and CO2 has been developed to synthesize a series of α,α-disubstituted γ-amino acids and γ-lactams with high efficiency and regioselectivity. Notably, CO2 released from the decarboxylation step can be reused for the subsequent carboxylation. Distinct from the previous reactions with the same type of substrates leading to simple decarboxylation and olefin hydroalkylation, this process involves additional CO2 sequestration, thus leading to olefin α-aminomethyl carboxylation. These findings not only provide new access to α,α-disubstituted γ-amino acids and γ-lactams but also serve as a proof of concept for CO2 reutilization in decarboxylation reactions.

The Concept of Photozymes: Short Peptides with Photoredox Catalytic Activity for Nucleophilic Additions to α-Phenyl Styrenes

Conventional photoredox catalytic additions of alcohols to olefins require additives, like thiophenol, to promote back electron transfer. The concept of “photozymes” assumes that forward and backward electron transfer steps in a photoredox catalytic cycle

Deaminative carbonylative coupling of alkylamines with styrenes under transition-metal-free conditions

A transition-metal-free deaminative carbonylation of alkylamines with styrenes has been developed. The reaction shows good functional group compatibility and various α,β-unsaturated ketones were obtained in moderate to good yields. The alkyl radical generated from Katritzky salts via base-promoted C-N bond cleavage is one of the key intermediates in this reaction. This journal is