4381-25-3

Basic information

• Product Name: (methylsulfonimidoyl)benzene
• Synonyms: Methylphenyl(imino)oxosulfur(VI);Methylphenyloxo(imino) sulfur(VI);Oxo(imino)(methyl)phenylsulfur(VI);S-Methyl-S-phenylsulfoximide;S-Methyl-S-phenylsulfoximine;S-Phenyl-S-methylsulfoximine;imino-methyl-oxo-phenyl-$l^{6}-sulfane
• CAS NO: 4381-25-3
• Molecular Formula: C₇H₉NOS
• Molecular Weight: 155.2175
• Mol File: 4381-25-3.mol
• Article Data: 79

Chemical Properties

• Melting Point: 34-36 °C
• Boiling Point: 237.8°Cat760mmHg
• Flash Point: 97.6°C
• Appearance: /
• Density: 1.14g/cm³
• CAS DataBase Reference: (methylsulfonimidoyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (methylsulfonimidoyl)benzene(4381-25-3)
• EPA Substance Registry System: (methylsulfonimidoyl)benzene(4381-25-3)

Safety Data

• Hazardous Substances Data: 4381-25-3(Hazardous Substances Data)

Usage

General Description

(Methylsulfonimidoyl)benzene, also known as mesityl sulfone, is a chemical compound with the molecular formula C9H10O2S. It is a white or colorless crystalline solid with a sweet, pungent odor. The compound is used as a solvent in organic chemical reactions and as a precursor to pharmaceuticals and dyes. It is also used as a stabilizer for plastics, as a fragrance ingredient in perfumes, and as a flavoring agent in the food industry. Additionally, (methylsulfonimidoyl)benzene has been studied for its potential anti-inflammatory and anti-microbial properties, making it a subject of interest in pharmaceutical and medical research. However, it is important to handle this compound with caution as it may cause skin irritation and is harmful if swallowed.

Upstream product

• 558-37-2 tert-butylethylene 
• 67087-35-8 N-chloro-S-methyl-S-phenyl sulfoximine 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 42397-39-7 Phenyl-methyl-sulfilimin 
• 36744-90-8 S,S-Diphenylsulfilimine 
• 452898-05-4 N-(2-trimethylsilylethylsulfonyl)-S-methyl-S-phenylsulfoximine 
• 452898-04-3 N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)-4-nitrobenzenesulfonamide 
• 688315-95-9 N-(trifluoroacetyl)-S-methyl-S-phenylsulfoximine 
• 952022-13-8 N-[methyl(oxo)(phenyl)-λ⁶-sulfanylidene]cyanamide 
• 946826-90-0 N-cyano-S-methyl-S-phenylsulfilimine 
• 100-68-5 methyl-phenyl-thioether 
• 42153-74-2 S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfoximide 
• 62-53-3 aniline 
• 1426922-36-2 N-[2-(4'-methylbenzenesulfonamido)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine 

Downstream Products

• 65975-55-5 (-)-(R)-Methylphenyloxosulfonium-bis-(methoxycarbonyl)-methylid 
• 37754-85-1 (N-Benzyl)-methylphenylsulfoximid 
• 24420-59-5 methyl phenyl sulfonium bismethoxycarbonylmethylide 
• 61177-70-6 N-methoxycarbonyl-S-methyl-S-phenylsulfoximines 
• 51076-22-3 5-hydroxy-1-oxo-1-phenyl-1λ⁶-[1,2]thiazine-4-carboxylic acid ethyl ester 
• 94126-32-6 N-bromo-S-methyl-S-phenyl sulfoximine 
• 85350-80-7 (+/-)-N-phenylcarbamyl S-methyl S-phenyl sulfoximine 
• 88375-87-5 C₁₅H₁₆N₂O₃S 
• 100326-78-1 (+)-(S)-1,5-diphenyl-1H-1λ⁴,2,4-thiadiazine 1-oxide 
• 128519-51-7 S-(2-aminostyryl)-S-phenylsulphoximide 
• 128519-52-8 S-(2-amino-4'-methylstyryl)-S-phenylsulphoximide 
• 54090-98-1 1-(Methylphenylsulfoxyliden)-3-cyclohexylharnstoff 
• 128547-26-2 S-(2-amino-4'-methoxstyryl)-S-phenylsulphoximide 
• 128547-27-3 S-(2-amino-2'-chlorostyryl)-S-phenylsulphoximide 

Relevant articles and documents

Iron-Catalyzed Amination of Sulfides and Sulfoxides with Azides in Photochemical Continuous Flow Synthesis

A photochemical (UVA) continuous flow process for the amination of thioethers and sulfoxides was performed with trichloroethoxysulfonyl azide in the presence of catalytic iron(III) acetylacetonate. Aromatic and aliphatic sulfilimines and sulfoximines were produced in high yields and short reaction times. The reaction with chiral sulfoxides was stereospecific, producing enantioenriched sulfoximines in excellent yields.

Synthesis and bioactivity of new phosphorylated R,R′-substituted sulfoximines

R,R′-disubstituted sulfoximines were phosphorylated with O,O-diethylchloro phosphate and phosphorothionate to obtain new organophosphorus compounds. After purification they were characterized by GC-MS and 1H-NMR. The toxicity of the synthesized

Flow Electrosynthesis of Sulfoxides, Sulfones, and Sulfoximines without Supporting Electrolytes

An efficient electrochemical flow process for the selective oxidation of sulfides to sulfoxides and sulfones and of sulfoxides toN-cyanosulfoximines has been developed. In total, 69 examples of sulfoxides, sulfones, andN-cyanosulfoximines have been synthesized in good to excellent yields and with high current efficiencies. The synthesis was assisted and facilitated through a supporting electrolyte-free, fully automated electrochemical protocol that highlights the advantages of flow electrolysis.

Chiral Dibenzopentalene-Based Conjugated Nanohoops through Stereoselective Synthesis

Conjugated nanohoops allow to investigate the effect of radial conjugation and bending on the involved π-systems. They can possess unexpected optoelectronic properties and their radially oriented π-system makes them attractive for host–guest chemistry. Be