441003-36-7

Basic information

• Product Name: 3-Butyn-2-ol, 4-(2,6-dimethylphenyl)-2-methyl-
• CAS NO: 441003-36-7
• Molecular Formula: C13H16O
• Molecular Weight: 188.269
• Mol File: 441003-36-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-Butyn-2-ol, 4-(2,6-dimethylphenyl)-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Butyn-2-ol, 4-(2,6-dimethylphenyl)-2-methyl-(441003-36-7)
• EPA Substance Registry System: 3-Butyn-2-ol, 4-(2,6-dimethylphenyl)-2-methyl-(441003-36-7)

Safety Data

• Hazardous Substances Data: 441003-36-7(Hazardous Substances Data)

Upstream product

• 86364-02-5 2,6-dimethylphenyl trifluoromethanesulphonate 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 576-26-1 2.6-dimethylphenol 
• 1342307-11-2 2,6-dimethylphenyl 1H-imidazole-1-sulfonate 
• 615-37-2 ortho-methylphenyl iodide 

Downstream Products

• 1243249-31-1 2-((4-methoxyphenyl)ethynyl)-1,3-dimethylbenzene 
• 1417574-52-7 N-(4-(2,6-dimethylphenyl)-2-methylbut-3-yn-2-yl)-4-methylbenzenesulfonamide 
• 349667-94-3 (3E)-2-methoxy-2-methyl-4-(2,6-dimethylphenyl)-3-butene 
• 267644-39-3 (3Z)-2-methoxy-2-methyl-4-(2,6-dimethylphenyl)-3-butene 
• 267644-38-2 (3Z)-2-methyl-4-(2,6-dimethylphenyl)-2-triethylsiloxy-3-butene 
• 441003-43-6 (3E)-2-methyl-4-(2,6-dimethylphenyl)-3-buten-2-ol 
• 441003-37-8 (3Z)-2-methyl-4-(2,6-dimethylphenyl)-3-buten-2-ol 

Relevant articles and documents

Multimetallic Ir-Sn3-catalyzed substitution reaction of π-activated alcohols with carbon and heteroatom nucleophiles

An atom economic and catalytic substitution reaction of π-activated alcohols by a multimetallic IreSn3 complex has been demonstrated. The multimetallic IreSn3 complex can be easily synthesized from the reaction between [Cp*IrCl2]2 and SnCl2. In presence of as little as 1 mol % of the catalyst three different types of π-activated alcohols, namely benzyl, allyl, and propargyl alcohols, have been successfully transformed into alkylated products using carbon (arenes, heteroarenes, allyltrimethylsilane, and 1,3-dicarbonyls), nitrogen (sulfonamides), oxygen (alcohols), and sulfur (thiols) nucleophiles in very high yields. An electrophilic mechanism is proposed from the Hammett correlation study.

Highly activated vinyl hydrogen in a significantly twisted styrene

(Chemical Equation Presented) The novel example of a vinylic hydrogen more reactive than a benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O quenching. In this paper, the full details of