442160-22-7

Basic information

• Product Name: 1-acetoxy-1-phenyl-2-(phenylsulfinyl)ethane
• Synonyms: 1-acetoxy-1-phenyl-2-(phenylsulfinyl)ethane
• CAS NO: 442160-22-7
• Molecular Weight: 288.367
• Mol File: 442160-22-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-acetoxy-1-phenyl-2-(phenylsulfinyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-acetoxy-1-phenyl-2-(phenylsulfinyl)ethane(442160-22-7)
• EPA Substance Registry System: 1-acetoxy-1-phenyl-2-(phenylsulfinyl)ethane(442160-22-7)

Safety Data

• Hazardous Substances Data: 442160-22-7(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 49639-26-1 erythro-2-(phenylsulfinyl)-1-phenyl-1-ethanol 
• 108-24-7 acetic anhydride 

Downstream Products

• 16619-62-8 (2-(phenylsulfinyl)vinyl)benzene 
• 442160-35-2 1-acetoxy-1-(2-naphthyl)-3-phenyl-2-(phenylsulfinyl)-2-propene 
• 442160-34-1 1-(2-naphthyl)-3-phenyl-2-(phenylsulfinyl)-2-propen-1-ol 
• 442160-46-5 3-acetoxy-1,5-diphenyl-4-(phenylsulfinyl)-4-penten-1-yne 
• 442160-33-0 3-acetoxy-1,5-diphenyl-2-(phenylsulfinyl)-1-pentene 
• 442160-45-4 1,5-diphenyl-4-(phenylsulfinyl)-4-penten-1-yn-3-ol 
• 442160-32-9 1,5-diphenyl-2-(phenylsulfinyl)-1-penten-3-ol 
• 257904-77-1 2-(3-phenylpropa-1,2-dienyl)naphthalene 
• 31552-02-0 (E)-penta-1,2,4-triene-1,5-diyldibenzene 
• 40110-66-5 (E)-2-phenyl-1-(phenylsulfinyl)ethene 

Relevant articles and documents

Palladium-Catalyzed Reductive [5+1] Cycloaddition of 3-Acetoxy-1,4-enynes with CO: Access to Phenols Enabled by Hydrosilanes

A new palladium-catalyzed reductive [5+1] cycloaddition of 3-acetoxy-1,4-enynes with CO, enabled by hydrosilanes, has been developed for delivering valuable functionalized phenols. This methodology employs hydrosilanes as the external reagent to facilitate the [5+1] carbonylative benzannulation. The reaction is a conceptually and mechanistically novel carbonylative cycloaddition route for the construction of substituted phenols, through the formation of four new chemical bonds, with excellent functional-group tolerance.