442636-24-0

Basic information

• Product Name: C₅₀H₅₆N₈O₂S₆
• Synonyms: C₅₀H₅₆N₈O₂S₆
• CAS NO: 442636-24-0
• Molecular Weight: 993.443
• Mol File: 442636-24-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅₀H₅₆N₈O₂S₆(CAS DataBase Reference)
• NIST Chemistry Reference: C₅₀H₅₆N₈O₂S₆(442636-24-0)
• EPA Substance Registry System: C₅₀H₅₆N₈O₂S₆(442636-24-0)

Safety Data

• Hazardous Substances Data: 442636-24-0(Hazardous Substances Data)

Upstream product

• 1014-99-9 1,4-bis(isothiocyanatomethyl)benzene 
• 442636-02-4 2,3-dimethyl-6-(4-benzyloxybutane)-5H,7H-2a-thia(2a-S^IV)-2,3,4a,7a-tetraazacyclopent[c,d]indene-1,4(2H,3H)-dithione 

Relevant articles and documents

Synthesis and properties of novel macrocyclic compounds bearing thiourea moieties by use of chemical feature of hypervalent sulfur

Macrocyclic compounds 5a-i bearing two tetraazathiapentalene frameworks were synthesized by the reaction of 10-S-3 tetraazathiapentalene derivatives 3a-f with compounds having various diisothiocyanate functions 4a-e. The reduction of the macrocyclic compounds with NaBH4 afforded the ring-opened macrocyclic compounds 11a-b and 11e-h by elimination of the hypervalent sulfur. The structures of these compounds were established by their spectral data and also by the X-ray crystallographic analysis of 11a. The other ring-opened macrocyclic compounds 14a and 14e-h that bear four thiourea groups were synthesized by alkaline hydrolysis of 5a and 5e-h in that elimination of the C=SIV moiety in the tetraazathiapentalene rings occurred.