442850-92-2Relevant articles and documents
Ruthenium Amide Complexes – Synthesis and Catalytic Activity in Olefin Metathesis and in Ring-Opening Polymerisation
Gawin, Anna,Pump, Eva,Slugovc, Christian,Kajetanowicz, Anna,Grela, Karol
supporting information, p. 1766 - 1774 (2018/05/14)
A set of olefin metathesis catalysts bearing a ruthenium amide moiety was synthesised. In the ruthenium amide form these complexes exhibit very low activity in standard metathesis reactions. However, a dramatic increase of activity was observed upon in si
Thiol-ene/oxidation tandem reaction under visible light photocatalysis: Synthesis of alkyl sulfoxides
Guerrero-Corella, Andrea,María Martinez-Gualda, Ana,Ahmadi, Fereshteh,Ming, Enrique,Fraile, Alberto,Alemán, José
supporting information, p. 10463 - 10466 (2017/09/25)
The photocatalyzed synthesis of sulfoxides from alkenes and thiols has been carried out using Eosin Y. This is a metal-free method which uses a low catalyst loading, atmospheric oxygen as the oxidant, and visible light conditions (green light). A mechanism has been proposed that is consistent with the experimental results.
Synthesis of indolines via a domino Cu-catalyzed amidation/cyclization reaction
Minatti, Ana,Buchwald, Stephen L.
scheme or table, p. 2721 - 2724 (2009/05/27)
(Chemical Equation Presented) A highly efficient one-pot procedure for the synthesis of indolines and their homologues based on a domino Cu-catalyzed amidation/nucleophilic substitution reaction has been developed. Substituted 2-iodophenethyl mesylates and related compounds afforded the corresponding products in excellent yields. No erosion of optical purity was observed when transforming enantiomerically pure mesylates under the reaction conditions.