4435-66-9

Basic information

• Product Name: 2,4,6-triphenylbenzenethiol
• Synonyms: 2,4,6-triphenylbenzenethiol;5'-Phenyl-m-terphenyl-2'-thiol
• CAS NO: 4435-66-9
• Molecular Formula: C₂₄H₁₈S
• Molecular Weight: 338.46472
• Mol File: 4435-66-9.mol
• Article Data: 1

Chemical Properties

• Melting Point: 145.5-146.5℃
• Appearance: /
• CAS DataBase Reference: 2,4,6-triphenylbenzenethiol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-triphenylbenzenethiol(4435-66-9)
• EPA Substance Registry System: 2,4,6-triphenylbenzenethiol(4435-66-9)

Safety Data

• Hazardous Substances Data: 4435-66-9(Hazardous Substances Data)

Usage

General Description

2,4,6-triphenylbenzenethiol is a chemical compound with the molecular formula C18H14S. It is a thiol, meaning it contains a sulfur atom bonded to a hydrogen atom, and has three phenyl (C6H5) groups attached to the benzene ring. 2,4,6-triphenylbenzenethiol is commonly used in organic synthesis and as a building block for creating more complex molecules. It is also known for its aromatic odor and is often used in the production of perfumes and fragrances. Due to its structure and properties, 2,4,6-triphenylbenzenethiol is also used as a corrosion inhibitor in the coating industry, and as a stabilizer for plastics and rubber products. Its chemical structure makes it a versatile and useful compound in various industrial and commercial applications.

Downstream Products

• 497944-02-2 (η5-cyclopentadienyl)(SC6H2Ph3-2,4,6)titanium dichloride 

Relevant articles and documents

The synthesis and characterization of metal derivatives of the new, conveniently prepared, bulky thiolato ligand HSC6H2-2,4,6-Ph3

The facile synthesis and characterisation of the new bulky thiol HSC6H2-2,4,6-Ph3 (HSTriph), 1, and two of its metal derivatives are described.The thiol was synthesized by the reaction of Li(OEt2)2Triph with sulfur followed by hydrolysis with dilute sulfuric acid.Treatment of HSTriph with n-BuLi afforded the monomeric Li(THF)3STriph, 2, and the reaction of 1 with the iron silylamide, Fe2, yielded the dimer 2, 3.The compounds were characterized by IR spectroscopy and the meetal derivatives by X-ray crystallography.Crystal data with MoKα(λ = 0.71069 Angstroem) at 130 K: 2, a = 9.392(2) Angstroem, b = 11.254(3) Angstroem, c = 15.304(5) Angstroem, α = 97.72(2) deg, β = 94.42(2) deg, γ = 100.93(7) deg, V = 1565.2(7) Angstroem3, Z = 2, space group P1, 3820 (I > 2?(I)) data, R = 0.07; 3, a = 12.035(3) Angstroem, b = 18.328(7) Angstroem, c = 16.505(5) Angstroem, β = 98.90(2) deg, V = 3597(2) Angstroem3, Z = 2, space group P21/n, 2518 (I > 2?(I)) data, R = 0.06. Key words: Transition metal thiolate / triphenylbenzenethiol