4436-90-2

Basic information

• Product Name: 2-phenylheptane-2-ol
• Synonyms: 2-phenylheptane-2-ol
• CAS NO: 4436-90-2
• Molecular Weight: 192.301
• Mol File: 4436-90-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-phenylheptane-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenylheptane-2-ol(4436-90-2)
• EPA Substance Registry System: 2-phenylheptane-2-ol(4436-90-2)

Safety Data

• Hazardous Substances Data: 4436-90-2(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 942-92-7 caprophenone 
• 110-43-0 n-pentyl methyl ketone 
• 2085-88-3 2-methyl-2-phenyloxirane 
• 109-72-8 n-butyllithium 
• 3262-89-3 triphenylboroxine 
• 110-62-3 pentanal 
• 693-03-8 n-butyl magnesium bromide 
• 98-83-9 isopropenylbenzene 
• 94287-29-3 N-Pent-(Z)-ylidene-N'-trityl-hydrazine 
• 98-86-2 acetophenone 
• 693-25-4 n-pentylmagnesium bromide 

Relevant articles and documents

Rhodium(I)/diene-catalyzed addition reactions of arylborons with ketones

Rh(I)/diene-catalyzed addition reactions of arylboroxines/arylboronic acids with unactivated ketones to form tertiary alcohols in good to excellent yields are described. By using C2-symmetric (3aR,6aR)-3,6-diaryl-1,3a,4,6a- tetrahydropentalenes as ligands, the asymmetric version of such an addition reaction, with up to 68% ee, was also realized.

AZO ANIONS IN SYNTHESIS. USE OF TRITYL- AND DIPHENYL-4-PYRIDYLMETHYLHYDRAZONES FOR REDUCTIVE C-C BOND FORMATION.

The lithium salts of trityl- and diphenyl-4-pyridylmethyl-hydrazones of both aldehydes and ketones react with electrophiles (alkyl halides, aldehydes, ketones, crotonates) at low temperature to form C-trapped azo compounds; these intermediates decompose homolytically with loss of nitrogen below room temperature and can be diverted in a synthetically useful way to alkanes, alkenes, alcohols or saturated esters.

Chemistry of Higher Order Mixed Organocuprates. 2. Reactions of Epoxides

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