4463-41-6

Basic information

• Product Name: 4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE
• Synonyms: P-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE;AKOS BRN-0003;4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE;4-FORMYLPHENYLBORONIC ACID PROPANEDIOL-1,3 CYCLIC ESTER;4-FORMYLBENZENEBORONIC ACID PROPANEDIOL-1,3 CYCLIC ESTER;4-Formylbenzeneboronic acid, propane-1,3-diol cyclic ester
• CAS NO: 4463-41-6
• Molecular Formula: C₁₀H₁₃BO₂
• Molecular Weight: 190
• Mol File: 4463-41-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 350.7 °C at 760 mmHg
• Flash Point: 165.9 °C
• Appearance: /
• Density: 1.12 g/cm³
• Vapor Pressure: 4.33E-05mmHg at 25°C
• Refractive Index: 1.511
• CAS DataBase Reference: 4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE(4463-41-6)
• EPA Substance Registry System: 4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE(4463-41-6)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 4463-41-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H11BO3/c12-8-9-2-4-10(5-3-9)11-13-6-1-7-14-11/h2-5,8H,1,6-7H2

Upstream product

• 5720-05-8 4-methylphenylboronic acid 
• 504-63-2 trimethyleneglycol 

Downstream Products

• 115377-87-2 N-((4-methoxyphenyl)(p-tolyl)methyl)benzenesulfonamide 
• 87567-60-0 2,3-dimethyl-4-(p-tolyl)-1-butene 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 99495-15-5 3-(p-tolyl)cyclohexan-1-one 
• 33757-36-7 (4-methylphenyl)(4-trifluoromethyl)methanol 
• 1043871-06-2 (Z)-1-phenyl-2-propyl-3-(p-tolyl)hex-2-en-1-ol 
• 1517-63-1 4-methylphenyl(phenyl)methanol 
• 42353-96-8 1-methyl-4-[(1E)-1-propyl-1-penten-1-yl]benzene 
• 838-22-2 4-methoxy-4'-methylbenzhydrol 
• 71434-61-2 1-(4-methylphenyl)-1-hexanol 
• 1370412-46-6 3-phenyl-N-(phenyl(p-tolyl)methyl)pyridin-2-amine 

Relevant articles and documents

Generation of organolithium compounds bearing super silyl ester and their application to Matteson rearrangement

It's super-silyl-fragilithyl-ester-aryl-docious: The super silyl group is a strong protecting group for carboxylic acids and provides a method for direct lithiation that is compatible with the ester moiety. Organolithium compounds bearing a super silyl ester react with a variety of electrophiles in high yields (see scheme). The reaction of lithiated super silyl chloroacetate with a boron compound gives α-functionalization of the ester moiety by Matteson rearrangement. Copyright

Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

Alkynes act not as substrates but as co-catalysts in the presence of a nickel catalyst, an organoboronate and an aldehyde to promote the addition reaction between the substrates in combination with H2O. The Royal Society of Chemistry 2005.