4511-39-1

Basic information

• Product Name: TERT-AMYL PEROXYBENZOATE 90
• Synonyms: tert-Amyl peroxy benzoate(in solution,content≤92%);TERT-AMYL PEROXYBENZOATE 90;tert-pentyl perbenzoate;TERT-AMYL PEROXYBENZOATE 90%;tert.-Amylperbenzoat;Luperox(R) TAP;Benzeneperoxycarboxylic acid 1,1-dimethylpropyl ester;Perbenzoic acid tert-amyl ester
• CAS NO: 4511-39-1
• Molecular Formula: C₁₂H₁₆O₃
• Molecular Weight: 208.25364
• EINECS: 224-831-5
• Mol File: 4511-39-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 298.9°Cat760mmHg
• Flash Point: 43 °C
• Appearance: /
• Density: 1.01 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.00123mmHg at 25°C
• Refractive Index: n20/D 1.501(lit.)
• CAS DataBase Reference: TERT-AMYL PEROXYBENZOATE 90(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-AMYL PEROXYBENZOATE 90(4511-39-1)
• EPA Substance Registry System: TERT-AMYL PEROXYBENZOATE 90(4511-39-1)

Safety Data

• Hazard Codes: O,Xi
• Statements: 7-10-36/37/38
• Safety Statements: 14-26-3/7-36/37/39
• RIDADR: 3105
• HazardClass: 5.2
• PackingGroup: II
• Hazardous Substances Data: 4511-39-1(Hazardous Substances Data)

Usage

General Description

TERT-AMYL PEROXYBENZOATE 90 is a chemical compound that is commonly used as a polymerization initiator and cross-linking agent in various industrial applications. It is a highly reactive organic peroxide with the chemical formula C15H24O3, and is classified as a hazardous substance due to its potential to cause skin and eye irritation, as well as being a strong oxidizing agent. This chemical is commonly used in the production of plastics, resins, and rubbers, as well as in the synthesis of various organic compounds. Safety precautions should be taken when handling TERT-AMYL PEROXYBENZOATE 90, including wearing protective clothing, goggles, and gloves, and ensuring proper ventilation in the work area.

InChI:InChI=1/C12H16O3/c1-4-12(2,3)15-14-11(13)10-8-6-5-7-9-10/h5-9H,4H2,1-3H3

Upstream product

• 3425-61-4 tert-amyl hydroperoxide 
• 98-88-4 benzoyl chloride 
• 75-85-4 tert-Amyl alcohol 
• 65-85-0 benzoic acid 

Downstream Products

• 4160-52-5 1-(4-methylphenyl)butan-1-one 
• 95971-74-7 N-(1-phenylbutyl)acetamide 

Relevant articles and documents

Iron-Catalyzed Dehydrative Alkylation of Propargyl Alcohol with Alkyl Peroxides to Form Substituted 1,3-Enynes

This paper reports a new method for the generation of substituted 1,3-enynes, whose synthesis by other methods could be a challenge. The dehydrative decarboxylative cascade coupling reaction of propargyl alcohol with alkyl peroxides is enabled by an iron catalyst and alkylating reagents. Primary, secondary, and tertiary alkyl groups can be introduced into 1,3-enynes, affording various substituted 1,3-enynes in moderate to good yields. Mechanistic studies suggest the involvement of a radical-polar crossover pathway.

Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source

Because of the lack of effective alkylating reagents, alkyl etherification of olefins with general alkyl groups has not been previously reported. In this work, a variety of alkyl diacyl peroxides and peresters generated from aliphatic acids have been found to enable the first iron-catalyzed alkyl etherification of olefins with general alkyl groups. Primary, secondary and tertiary aliphatic acids are suitable for this reaction, delivering products with yields up to 97 %. Primary and secondary alcohols react well, affording products in up to 91 % yield.