451501-37-4

Basic information

• Product Name: (4E,6Z)-9-phenylnona-4,6-dienal
• Synonyms: (4E,6Z)-9-phenylnona-4,6-dienal
• CAS NO: 451501-37-4
• Molecular Weight: 214.307
• Mol File: 451501-37-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4E,6Z)-9-phenylnona-4,6-dienal(CAS DataBase Reference)
• NIST Chemistry Reference: (4E,6Z)-9-phenylnona-4,6-dienal(451501-37-4)
• EPA Substance Registry System: (4E,6Z)-9-phenylnona-4,6-dienal(451501-37-4)

Safety Data

• Hazardous Substances Data: 451501-37-4(Hazardous Substances Data)

Upstream product

• 112505-94-9 (E)-2-(5-tert-butyldimethylsilyl-oxypent-1-enyl)-1,3,2-benzodioxaborole 
• 61362-77-4 5-[tert-butyldimethylsilyloxy]pent-1-yne 
• 952687-93-3 (4E,6Z)-9-phenylnona-4,6-dien-1-ol 

Relevant articles and documents

Rhodium(I)-catalyzed intramolecular hydroacylation of 4,6-dienals: Novel synthesis of cycloheptenones

Rhodium(I)-catalyzed hydroacylation of 4,6-dienals was investigated. Hydroacylation of 4,6-dienals with a substituent at the C7 position produced cycloheptenone derivatives as the major products, while the cyclization of 4,6-dienals with no substituent at the terminus of the diene moiety preferentially gave cyclopentanone derivatives. The olefinic geometry of the diene moiety in 4,6-dienals also affected the reaction course, and the cyclization of substrates with an E-olefin at the C6 position produced cycloheptenone derivatives as the major products, while a cyclopentanone derivative was obtained from a substrate with a Z-olefin at the C6 position. Georg Thieme Verlag Stuttgart.