453509-56-3

Basic information

• Product Name: 1,2-bis[(6-L-menthoxymethyl-2-pyridyl)ethynyl]benzene
• Synonyms: 1,2-bis[(6-L-menthoxymethyl-2-pyridyl)ethynyl]benzene
• CAS NO: 453509-56-3
• Molecular Weight: 616.887
• Mol File: 453509-56-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-bis[(6-L-menthoxymethyl-2-pyridyl)ethynyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-bis[(6-L-menthoxymethyl-2-pyridyl)ethynyl]benzene(453509-56-3)
• EPA Substance Registry System: 1,2-bis[(6-L-menthoxymethyl-2-pyridyl)ethynyl]benzene(453509-56-3)

Safety Data

• Hazardous Substances Data: 453509-56-3(Hazardous Substances Data)

Upstream product

• 21792-52-9 1,2-diethynylbenzene 
• 453509-58-5 2-bromo-6-(L-menthyloxymethyl)pyridine 
• 557789-12-5 (6-bromopyridin-2-yl)methyl methanesulfonate 
• 496840-11-0 2-bromo-6-(iodomethyl)pyridine 
• 33674-96-3 2-bromo-6-(hydroxymethyl)pyridine 
• 2216-51-5 (-)-menthol 

Relevant articles and documents

Self-assembly and substituent effect of copper(I) complexes with 1,2-bis(2-pyridylethynyl)benzene ligands

The reaction of 1,2-bis(2-pyridylethynyl)benzenes (L1-L5) with copper(I) ions proceeded smoothly to afford mononuclear copper(I) chelate complexes CL1-CL3 or dinuclear copper(I) molecular rectangular boxes, CL4 and CL5, in excellent yields, depending on the size of the substituent. If a ligand with a small substituent was used, the self-assembly of a mononuclear copper(I) chelate complex was achieved. If a ligand with a bulky substituent was used, the self-assembly of dinuclear copper(I) molecular rectangular boxes was achieved. The equilibrium between these two copper(I) complexes was also observed in solution.